一种基于柔性锰（II）-席夫碱的金属有机框架的电化学还原
The electrochemical reduction of a flexible Mn(II) salen-based metal-organic framework.
作者信息
Solomon Marcello B, Hua Carol, Chan Bun, Church Tamara L, Cohen Seth M, Kubiak Clifford P, Jolliffe Katrina A, D'Alessandro Deanna M
机构信息
School of Chemistry, The University of Sydney, New South Wales 2006, Australia.
School of Chemistry, The University of Melbourne, Parkville, Vic, 3010, Australia.
出版信息
Dalton Trans. 2021 Sep 28;50(37):12821-12825. doi: 10.1039/d1dt02589a.
A new metal-organic framework (MOF) containing a Mn(II) salen complex (BET surface area = 967 ± 6 m g) undergoes a reversible crystalline-to-amorphous transformation. Experimental studies and computational calculations show that the MOF is stable to a one-electron reduction at more anodic potentials than the corresponding discrete complex.
一种含有Mn(II) 双水杨醛缩乙二胺络合物（BET表面积 = 967 ± 6 m²/g）的新型金属有机框架（MOF）经历了可逆的晶态到非晶态转变。实验研究和计算表明，该MOF在比相应离散络合物更正的阳极电位下对单电子还原稳定。
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