Serra Albert, Serra-Parareda Ferran, Vilaseca Fabiola, Delgado-Aguilar Marc, Espinach Francesc X, Tarrés Quim
LEPAMAP-PRODIS Research Group, University of Girona, Maria Aurèlia Capmany 61, 17003 Girona, Spain.
Advanced Biomaterials and Nanotechnology, Department of Chemical Engineering, University of Girona, Maria Aurèlia Capmany 61, 17003 Girona, Spain.
Materials (Basel). 2021 Aug 24;14(17):4787. doi: 10.3390/ma14174787.
The textile sector produces yearly great quantities of cotton byproducts, and the major part is either incinerated or landfilled, resulting in serious environmental risks. The use of such byproducts in the composite sector presents an attractive opportunity to valorize the residue, reduce its environmental impact, and decrease the pressure on natural and synthetic resources. In this work, composite materials based on polypropylene and dyed cotton byproducts from the textile industry were manufactured. The competitiveness of the resulting composites was evaluated from the analyses, at macro and micro scales, of the flexural modulus. It was observed that the presence of dyes in cotton fibers, also a byproduct from the production of denim items, notably favored the dispersion of the phases in comparison with other cellulose-rich fibers. Further, the presence of a coupling agent, in this case, maleic anhydride grafted polypropylene, enhanced the interfacial adhesion of the composite. As a result, the flexural modulus of the composite at 50 wt.% of cotton fibers enhanced by 272% the modulus of the matrix. From the micromechanics analysis, using the Hirsch model, the intrinsic flexural modulus of cotton fibers was set at 20.9 GPa. Other relevant micromechanics factors were studied to evaluate the contribution and efficiency of the fibers to the flexural modulus of the composite. Overall, the work sheds light on the potential of cotton industry byproducts to contribute to a circular economy.
纺织部门每年都会产生大量的棉花副产品,其中大部分要么被焚烧,要么被填埋,从而带来严重的环境风险。在复合材料领域使用这些副产品为实现残渣增值、减少其环境影响以及减轻对天然和合成资源的压力提供了一个有吸引力的机会。在这项工作中,制造了基于聚丙烯和纺织工业染色棉花副产品的复合材料。通过在宏观和微观尺度上对弯曲模量的分析,评估了所得复合材料的竞争力。观察到,与其他富含纤维素的纤维相比,棉花纤维(也是牛仔布制品生产中的副产品)中染料的存在显著有利于相的分散。此外,在这种情况下,偶联剂马来酸酐接枝聚丙烯的存在增强了复合材料的界面附着力。结果,在棉纤维含量为50 wt.%时,复合材料的弯曲模量比基体模量提高了272%。通过使用赫希模型进行微观力学分析,确定棉纤维的固有弯曲模量为20.9 GPa。还研究了其他相关的微观力学因素,以评估纤维对复合材料弯曲模量的贡献和效率。总体而言,这项工作揭示了棉花工业副产品对循环经济做出贡献的潜力。