• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

从酸洗废液中获取氯化亚铁FeCl·4HO及其特性研究

Obtention and Characterization of Ferrous Chloride FeCl·4HO from Water Pickling Liquors.

作者信息

Alcaraz Lorena, Sotillo Belén, Marco José F, Alguacil Francisco J, Fernández Paloma, López Félix A

机构信息

Centro Nacional de Investigaciones Metalúrgicas (CENIM), Consejo Superior de Investigaciones Científicas (CSIC), Avda. Gregorio del Amo, 8, 28040 Madrid, Spain.

Departamento de Física de Materiales, Facultad de Ciencias Físicas, Universidad Complutense de Madrid (UCM), 28040 Madrid, Spain.

出版信息

Materials (Basel). 2021 Aug 26;14(17):4840. doi: 10.3390/ma14174840.

DOI:10.3390/ma14174840
PMID:34500936
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8432721/
Abstract

As a hazardous waste, water pickling liquors must be properly treated. An alternative consists of promoting the formation of ferrous salts from this residue due to their higher ferrous content. Since FeCl·4HO is widely used in several applications, obtaining pure crystals of this material appears to be an interesting prospect. However, this compound has scarcely been investigated. In the present work, FeCl·4HO crystals were obtained from water pickling liquors. Their structural and morphological characteristics were investigated by X-ray diffraction, scanning electron microscopy as well as Mössbauer spectroscopy. In addition, the photoluminescence study of the obtained samples was also assessed. It was observed that after some aging time, the obtained crystals changed in colour from green to more yellowish. As such, the aged sample was also evaluated, and their structural characteristics were compared with the original crystals. Despite this, the obtained crystals exhibit a FeCl·4HO structure, which is not modified with the aging of the sample.

摘要

作为一种危险废物，水酸洗液必须得到妥善处理。一种替代方法是利用这种残渣中较高的亚铁含量来促进亚铁盐的形成。由于FeCl·4HO在多种应用中被广泛使用，获得这种材料的纯晶体似乎是一个有趣的前景。然而，对该化合物的研究很少。在本工作中，从水酸洗液中获得了FeCl·4HO晶体。通过X射线衍射、扫描电子显微镜以及穆斯堡尔谱对其结构和形态特征进行了研究。此外，还对所得样品进行了光致发光研究。观察到经过一段时间的老化后，所得晶体的颜色从绿色变为更偏黄色。因此，对老化样品也进行了评估，并将其结构特征与原始晶体进行了比较。尽管如此，所得晶体呈现出FeCl·4HO结构，且不会因样品老化而改变。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/0070af73903e/materials-14-04840-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/7ecd44eca321/materials-14-04840-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/08f76bb523e5/materials-14-04840-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/8efc83479c89/materials-14-04840-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/a3f02484c559/materials-14-04840-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/296e482b0105/materials-14-04840-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/4d276dec69c4/materials-14-04840-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/cc1708a034e9/materials-14-04840-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/4e4e5123b34e/materials-14-04840-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/dc945e9f7f91/materials-14-04840-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/80d2668b51da/materials-14-04840-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/f1a7d7efcd80/materials-14-04840-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/0070af73903e/materials-14-04840-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/7ecd44eca321/materials-14-04840-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/08f76bb523e5/materials-14-04840-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/8efc83479c89/materials-14-04840-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/a3f02484c559/materials-14-04840-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/296e482b0105/materials-14-04840-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/4d276dec69c4/materials-14-04840-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/cc1708a034e9/materials-14-04840-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/4e4e5123b34e/materials-14-04840-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/dc945e9f7f91/materials-14-04840-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/80d2668b51da/materials-14-04840-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/f1a7d7efcd80/materials-14-04840-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e4b5/8432721/0070af73903e/materials-14-04840-g012.jpg

相似文献

1
Obtention and Characterization of Ferrous Chloride FeCl·4HO from Water Pickling Liquors.从酸洗废液中获取氯化亚铁FeCl·4HO及其特性研究
Materials (Basel). 2021 Aug 26;14(17):4840. doi: 10.3390/ma14174840.
2
Minimizing the creation of spent pickling liquors in a pickling process with high-concentration hydrochloric acid solutions: mechanism and evaluation method.在高浓度盐酸酸洗过程中减少废酸液生成的方法：机理与评价方法。
J Environ Manage. 2012 May 15;98:147-54. doi: 10.1016/j.jenvman.2011.12.027. Epub 2012 Jan 20.
3
Preparation of nano-sized magnetic particles from spent pickling liquors by ultrasonic-assisted chemical co-precipitation.通过超声辅助化学共沉淀法从废酸洗液中制备纳米级磁性颗粒。
J Hazard Mater. 2009 Apr 30;163(2-3):1173-8. doi: 10.1016/j.jhazmat.2008.07.095. Epub 2008 Jul 29.
4
Preliminary study of treatment of sulphuric pickling water waste from steelmaking by bio-oxidation with Thiobacillus ferrooxidans.
FEMS Microbiol Rev. 1994 Aug;14(4):397-404. doi: 10.1111/j.1574-6976.1994.tb00114.x.
5
Highly selective removal of Zn(II) ion from hot-dip galvanizing pickling waste with amino-functionalized Fe3O4@SiO2 magnetic nano-adsorbent.用氨基功能化 Fe3O4@SiO2 磁性纳米吸附剂从热浸镀锌酸洗废水中高选择性去除 Zn(II)离子。
J Colloid Interface Sci. 2016 Jan 15;462:235-42. doi: 10.1016/j.jcis.2015.10.011. Epub 2015 Oct 9.
6
Structure and Population of Complex Ionic Species in FeCl Aqueous Solution by X-ray Absorption Spectroscopy.X 射线吸收光谱法研究 FeCl 水溶液中复杂离子物种的结构和组成。
Molecules. 2022 Jan 19;27(3):642. doi: 10.3390/molecules27030642.
7
Ni3Cl2.1(OH)3.9·4H2O, the Ni analogue to Mg3Cl2(OH)4·4H2O.Ni3Cl2.1(OH)3.9·4H2O，即Mg3Cl2(OH)4·4H2O的镍类似物。
Inorg Chem. 2014 May 5;53(9):4316-24. doi: 10.1021/ic500251x. Epub 2014 Apr 22.
8
Biosynthesis of nanocrystal akaganéite from FeCl2 solution oxidized by Acidithiobacillus ferrooxidans cells.嗜酸氧化亚铁硫杆菌细胞氧化FeCl2溶液生物合成纳米晶四方纤铁矿
Environ Sci Technol. 2008 Jun 1;42(11):4165-9. doi: 10.1021/es702933v.
9
Neutralization of red mud with pickling waste liquor using Taguchi's design of experimental methodology.采用田口实验设计方法用酸洗废液中和赤泥。
Waste Manag Res. 2012 Sep;30(9):922-30. doi: 10.1177/0734242X12448518. Epub 2012 Jun 29.
10
Ferrous ion-stimulated alkane expiration in rats treated with carbon tetrachloride.四氯化碳处理的大鼠中，亚铁离子刺激的烷烃呼出
Toxicology. 1983 Sep;28(1-2):29-36. doi: 10.1016/0300-483x(83)90103-8.

引用本文的文献

1
Mössbauer Spectroscopy with a High Velocity Resolution in the Studies of Nanomaterials.纳米材料研究中具有高速度分辨率的穆斯堡尔光谱学。
Nanomaterials (Basel). 2022 Oct 25;12(21):3748. doi: 10.3390/nano12213748.
2
The Effect of the Presence of Amino Acids on the Precipitation of Inorganic Chemical-Garden Membranes: Biomineralization at the Origin of Life.氨基酸存在对无机化学花园膜沉淀的影响：生命起源的生物矿化。
Langmuir. 2022 Aug 30;38(34):10538-10547. doi: 10.1021/acs.langmuir.2c01345. Epub 2022 Aug 16.

本文引用的文献

1
Room-Temperature Reduction of Graphene Oxide in Water by Metal Chloride Hydrates: A Cleaner Approach for the Preparation of Graphene@Metal Hybrids.金属氯化物水合物在水中室温还原氧化石墨烯：一种制备石墨烯@金属杂化物的更清洁方法
Nanomaterials (Basel). 2020 Jun 28;10(7):1255. doi: 10.3390/nano10071255.
2
Pyrolysis of different biomass pre-impregnated with steel pickling waste liquor to prepare magnetic biochars and their use for the degradation of metronidazole.不同生物质的热解——用钢铁酸洗废液预浸渍生物质——以制备磁性生物炭及其在甲硝唑降解中的应用。
Bioresour Technol. 2019 Oct;289:121613. doi: 10.1016/j.biortech.2019.121613. Epub 2019 Jun 7.
3
Preparation of multifunctional Janus nanoparticles on the basis of SPIONs as targeted drug delivery system.
基于 SPIONs 的多功能两性纳米粒子的制备及其作为靶向药物传递系统的研究。
Int J Pharm. 2019 Mar 25;559:1-12. doi: 10.1016/j.ijpharm.2019.01.020. Epub 2019 Jan 18.
4
Synthesis and characterization of rice straw/Fe3O4 nanocomposites by a quick precipitation method.快速沉淀法合成水稻秸秆/Fe3O4 纳米复合材料及其性能表征。
Molecules. 2013 Jun 5;18(6):6597-607. doi: 10.3390/molecules18066597.
5
Minimizing the creation of spent pickling liquors in a pickling process with high-concentration hydrochloric acid solutions: mechanism and evaluation method.在高浓度盐酸酸洗过程中减少废酸液生成的方法：机理与评价方法。
J Environ Manage. 2012 May 15;98:147-54. doi: 10.1016/j.jenvman.2011.12.027. Epub 2012 Jan 20.