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室温硫化硅橡胶的阻燃性和优异的电绝缘性能

Flame Retardancy and Excellent Electrical Insulation Performance of RTV Silicone Rubber.

作者信息

Nazir Muhammad Tariq, Khalid Arslan, Kabir Imrana, Wang Cheng, Baena Juan-Carlos, Akram Shakeel, Bhutta Muhammad Shoaib, Yasin Ghulam, Phung Bao Toan, Yeoh Guan Heng

机构信息

School of Mechanical and Manufacturing Engineering, University of New South Wales, Sydney, NSW 2052, Australia.

Institut d'Electronique et des Systèmes (IES), UMR 5214, CNRS, Université de Montpellier, 34095 Montpellier, France.

出版信息

Polymers (Basel). 2021 Aug 25;13(17):2854. doi: 10.3390/polym13172854.

Abstract

Room temperature vulcanized (RTV) silicone rubber filled with aluminum trihydrate (ATH) is substantially engaged in electrical outdoor insulation applications. The pristine silicone rubber is highly combustible. ATH filled silicone rubber offers excellent electrical insulation but lacks in providing adequate flame retardancy. This short communication reports the novel results on improved flame retardancy of pristine and ATH filled silicone rubber whilst retaining the electrical insulation properties to a great extent. Results suggest that the presence of only one percent of graphene nanoplatelets with ATH sharply reduces the heat release rate and rate of smoke release. A minor reduction in dielectric breakdown strength and volume resistivity is noticed. Furthermore, permittivity and dielectric loss at power frequency suggest that a marginal 1% concentration of nanoplatelet with ATH is an excellent approach to fabricate flame retardant silicone rubber with an acceptable electrical insulation level.

摘要

填充有三水合铝(ATH)的室温硫化(RTV)硅橡胶主要用于户外电气绝缘应用。原始硅橡胶具有高度可燃性。填充有ATH的硅橡胶具有优异的电绝缘性,但缺乏足够的阻燃性。本简短通讯报道了在很大程度上保留电绝缘性能的同时提高原始硅橡胶和填充有ATH的硅橡胶阻燃性的新结果。结果表明,仅1%的石墨烯纳米片与ATH一起存在时,可大幅降低热释放速率和烟雾释放速率。介电击穿强度和体积电阻率略有降低。此外,工频下的电容率和介电损耗表明,1%的纳米片与ATH的少量浓度是制造具有可接受电绝缘水平的阻燃硅橡胶的极佳方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/be56/8434291/2f14df9e77e9/polymers-13-02854-g001.jpg

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