Chen Yun, Wang Kun, Zhang Chong, Yang Wei, Qiao Bo, Yin Li
Beijing Institute of Smart Energy, Beijing 102299, China.
Polymers (Basel). 2023 Mar 22;15(6):1584. doi: 10.3390/polym15061584.
Silicone rubber (SIR) has been widely used in electrical insulation fields, and the introduction of new materials is very important for the performance improvement of SIR composites. In this work, four different fillers, including aluminium hydroxide (ATH), yimonite (YMT), boron nitride (BN) and mica-filled SIR composites were prepared, and the vulcanization behavior, mechanical properties, insulation performance and hydrophobicity of the SIR composites were investigated and compared. Both BN- and mica-filled SIR composites showed excellent insulation performance, while the ATH-filled SIR composite exhibited the best mechanical properties with an elongation at break of 230% and a tensile strength of 2.9 MPa. The SIR/BN composite showed a breakdown strength of 29.2 kV/mm with a 5% failure rate. The addition of YMT deteriorated the insulation performance of SIR but improved the elongation at break and hydrophobicity, with an elongation at break increasing from 115% to 410% and the static contact angle improving from 109.8° to 115.6°.
硅橡胶(SIR)已广泛应用于电气绝缘领域,引入新型材料对于提高SIR复合材料的性能非常重要。在本工作中,制备了四种不同的填料填充的SIR复合材料,包括氢氧化铝(ATH)、叶蛇纹石(YMT)、氮化硼(BN)和云母,研究并比较了SIR复合材料的硫化行为、力学性能、绝缘性能和疏水性。BN填充和云母填充的SIR复合材料均表现出优异的绝缘性能,而ATH填充的SIR复合材料表现出最佳的力学性能,其断裂伸长率为230%,拉伸强度为2.9MPa。SIR/BN复合材料的击穿强度为29.2kV/mm,失效率为5%。添加YMT会降低SIR的绝缘性能,但会提高断裂伸长率和疏水性,断裂伸长率从115%增加到410%,静态接触角从109.8°提高到115.6°。