Yu Xiaoniu, He Zhihai, Li Xianyan
Jiangsu Key Laboratory of Construction Materials, Nanjing, 211189, China.
College of Civil Engineering and Architecture, Wenzhou University, Wenzhou, 325035, China.
Environ Sci Pollut Res Int. 2022 Feb;29(8):11219-11231. doi: 10.1007/s11356-021-16401-0. Epub 2021 Sep 16.
The microbial induced mineral precipitation can be used to modify and improve the performance of construction materials and can partially replace ordinary Portland cement. Microbially induced carbonate precipitation (MICP) mainly uses the urease secreted during the growth of urease-producing bacteria (UPB) to hydrolyze urea produce CO and reacts with Ca to form CaCO. Microbially induced struvite precipitation (MISP) mainly uses the urease to decompose urea to produce NH. In the presence of hydrogen phosphate and magnesium ions, the struvite can be precipitated. The elemental composition and chemical composition of the precipitates produced by the MICP and MISP processes are analyzed by energy dispersive X-ray spectroscopy (EDS) and powder X-ray diffraction analysis (XRD). The morphology of the precipitates can be observed by scanning electron microscope (SEM). Compared with the initial porosity, the MICP method can reduce the initial porosity of the sand column by 2.98% within 90 min. However, the MISP is only 1.45%. The permeability coefficient of the sand column can be effectively reduced in the MICP process. The total content of cementitious materials is 27.71g and 13.16g in MICP- and MISP-cemented sand columns, respectively. The MICP technology can improve the strength of alkali-activated mortars under different pH values of the UPB solution.
微生物诱导矿物沉淀可用于改性和改善建筑材料的性能,并可部分替代普通硅酸盐水泥。微生物诱导碳酸盐沉淀(MICP)主要利用产脲酶细菌(UPB)生长过程中分泌的脲酶水解尿素产生CO₂,并与Ca²⁺反应形成CaCO₃。微生物诱导鸟粪石沉淀(MISP)主要利用脲酶分解尿素产生NH₄⁺。在磷酸氢根和镁离子存在的情况下,可沉淀出鸟粪石。通过能量色散X射线光谱(EDS)和粉末X射线衍射分析(XRD)对MICP和MISP过程产生的沉淀物的元素组成和化学成分进行分析。沉淀物的形态可通过扫描电子显微镜(SEM)观察。与初始孔隙率相比,MICP方法可在90分钟内将砂柱的初始孔隙率降低2.98%。然而,MISP仅为1.45%。在MICP过程中,砂柱的渗透系数可有效降低。MICP和MISP胶结砂柱中胶凝材料的总含量分别为27.71g和13.16g。MICP技术可提高不同pH值的UPB溶液作用下碱激发砂浆的强度。