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使用生物灌浆对混凝土进行裂缝密封:增强机械强度和防水性的可持续方法。

Crack Sealing in Concrete with Biogrout: Sustainable Approach to Enhancing Mechanical Strength and Water Resistance.

作者信息

Wang Jian, Ji Shengjie, Huang Shuguang, Jiang Zihang, Wang Siqi, Zhang Huaiqi, Wang Zijian, Zhang Junfei

机构信息

Beijing Building Research Institute Corporation Ltd., China State Construction Engineering Corporation, Beijing 100076, China.

Institute of Acoustics, Chinese Academy of Sciences, Beijing 100190, China.

出版信息

Materials (Basel). 2024 Dec 23;17(24):6283. doi: 10.3390/ma17246283.

Abstract

Concrete, as the most widely used construction material globally, is prone to cracking under the influence of external factors such as mechanical loads, temperature fluctuations, chemical corrosion, and freeze-thaw cycles. Traditional concrete crack repair methods, such as epoxy resins and polymer mortars, often suffer from a limited permeability, poor compatibility with substrates, and insufficient long-term durability. Microbial biogrouting technology, leveraging microbial-induced calcium carbonate precipitation (MICP), has emerged as a promising alternative for crack sealing. This study aimed to explore the potential of for repairing concrete cracks to enhance compressive strength and permeability performance post-repair. Experiments were conducted to evaluate the bacterial growth cycle and urease activity under varying concentrations of Ca. The results indicated that the optimal time for crack repair occurred 24-36 h after bacterial cultivation. Additionally, the study revealed an inhibitory effect of high calcium ion concentrations on urease activity, with the optimal concentration identified as 1 mol/L. Compressive strength and water absorption tests were performed on repaired concrete specimens. The compressive strength of specimens with cracks of varying dimensions improved by 4.01-11.4% post-repair, with the highest improvement observed for specimens with 1 mm wide and 10 mm deep cracks, reaching an increase of 11.4%. In the water absorption tests conducted over 24 h, the average mass water absorption rate decreased by 31.36% for specimens with 0.5 mm cracks, 29.06% for 1 mm cracks, 27.9% for 2 mm cracks, and 28.2% for 3 mm cracks. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses confirmed the formation of dense calcium carbonate precipitates, with the SEM-EDS results identifying calcite and vaterite as the predominant self-healing products. This study underscores the potential of MICP-based microbial biogrouting as a sustainable and effective solution for enhancing the mechanical and durability properties of repaired concrete.

摘要

混凝土作为全球使用最广泛的建筑材料,在机械荷载、温度波动、化学腐蚀和冻融循环等外部因素的影响下容易开裂。传统的混凝土裂缝修复方法,如环氧树脂和聚合物砂浆,往往存在渗透性有限、与基层的兼容性差以及长期耐久性不足等问题。利用微生物诱导碳酸钙沉淀(MICP)的微生物生物注浆技术已成为一种有前景的裂缝密封替代方法。本研究旨在探索修复混凝土裂缝以提高修复后抗压强度和渗透性能的潜力。进行了实验以评估不同钙浓度下细菌的生长周期和脲酶活性。结果表明,裂缝修复的最佳时间出现在细菌培养后24 - 36小时。此外,研究还揭示了高钙离子浓度对脲酶活性的抑制作用,确定最佳浓度为1 mol/L。对修复后的混凝土试件进行了抗压强度和吸水率测试。不同尺寸裂缝试件修复后的抗压强度提高了4.01 - 11.4%,其中宽度为1 mm、深度为10 mm裂缝的试件提高幅度最大,达到11.4%。在24小时的吸水率测试中,0.5 mm裂缝试件的平均质量吸水率下降了31.36%,1 mm裂缝试件下降了29.06%,2 mm裂缝试件下降了27.9%,3 mm裂缝试件下降了28.2%。X射线衍射(XRD)和扫描电子显微镜(SEM)分析证实了致密碳酸钙沉淀的形成,SEM - EDS结果确定方解石和球霰石为主要的自修复产物。本研究强调了基于MICP的微生物生物注浆作为增强修复后混凝土力学和耐久性性能的可持续有效解决方案的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0c00/11679691/b363f9b67dcd/materials-17-06283-g001.jpg

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