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用于高效钠存储的氮/磷共掺杂硬碳纳米纤维的原位机理与动力学研究

Operando mechanistic and dynamic studies of N/P co-doped hard carbon nanofibers for efficient sodium storage.

作者信息

Wang Liaoliao, Wang Juan, Ng Dickon H L, Li Sheng, Zou Bobo, Cui Yingxue, Liu Xianhu, El-Khodary Sherif A, Qiu Jingxia, Lian Jiabiao

机构信息

Key Laboratory of Zhenjiang, Institute for Energy Research, Jiangsu University, Zhenjiang, 212013, P. R. China.

Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong, P. R. China.

出版信息

Chem Commun (Camb). 2021 Sep 21;57(75):9610-9613. doi: 10.1039/d1cc03961j.

Abstract

Raman and electrochemical results reveal that Na adsorbs on the surface/defective sites of N/P-HCNF and inserts randomly into its turbostratic nanodomains in the dilute state without a staged formation, which can facilitate fast Na diffusion kinetics for efficient sodium storage.

摘要

拉曼光谱和电化学结果表明,钠吸附在N/P-HCNF的表面/缺陷位点上,并在稀释状态下随机插入其乱层纳米域中,不会形成分层结构,这有助于实现快速的钠扩散动力学,从而实现高效的钠存储。

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