Departamento de Medio Ambiente y Agronomía, Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria-Consejo Superior de Investigaciones Científicas (INIA-CSIC), Madrid, Spain.
J Sep Sci. 2022 Jan;45(1):233-245. doi: 10.1002/jssc.202100581. Epub 2021 Oct 4.
The use of molecularly imprinted polymers in sample preparation as selective sorbent materials has received great attention during the last years leading to analytical methods with unprecedented selectivity. However, with the progressive implementation of Green Analytical Chemistry principles, it is necessary to critically review the greenness of synthesis and further use of molecularly imprinted polymers in sample preparation. Accordingly, in the present review, the different steps and strategies for the preparation of molecularly imprinted polymers, the used reagents, as well as their incorporation to microextraction techniques are reviewed from a green perspective and recent alternatives to make the use of molecularly imprinted polymers more sustainable are provided.
近年来，分子印迹聚合物作为选择性吸附材料在样品制备中的应用受到了极大的关注，由此产生了具有空前选择性的分析方法。然而，随着绿色分析化学原则的逐步实施，有必要批判性地审查分子印迹聚合物在样品制备中的合成和进一步使用的绿色性。因此，在本综述中，从绿色角度综述了分子印迹聚合物的制备的不同步骤和策略、所用试剂以及将其纳入微萃取技术的情况，并提供了一些使分子印迹聚合物的使用更可持续的替代方案。
