镍二价离子奇数组态的理论研究
Theoretical Investigation of the Odd Configurations of Ni ii.
作者信息
Shadmi Y, Caspi E
出版信息
J Res Natl Bur Stand A Phys Chem. 1972 Mar-Apr;76A(2):125-136. doi: 10.6028/jres.076A.013.
Abstract
Two groups of odd levels in Ni ii were investigated: those belonging to the complex 3 4 + 3 44+3 5 and those belonging to the configuration 3 4. In the first group the calculated positions of the levels were fit to the positions of the 174 observed levels with an rms error of 133 cm. The fit for the second group was based on 60 observed levels and had an rms error of 25 cm. The predictions of this investigation helped in the discovery of many of the observed levels.
摘要
对镍二价离子中的两组奇数能级进行了研究
属于3d⁴+3d⁴4s+3d⁵组态的能级和属于3d⁴组态的能级。在第一组中，计算出的能级位置与174个观测能级的位置相拟合，均方根误差为133厘米。第二组的拟合基于60个观测能级，均方根误差为25厘米。本次研究的预测有助于发现许多观测到的能级。
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本文引用的文献
1
The Second Spectrum of Nickel (Ni II).镍（II）的第二光谱
J Res Natl Bur Stand A Phys Chem. 1970 Nov-Dec;74A(6):801-855. doi: 10.6028/jres.074A.067.
2
Effective Interactions in the Even Configurations of the Third Spectra of the Iron Group.铁族第三光谱偶数组态中的有效相互作用
J Res Natl Bur Stand A Phys Chem. 1969 Mar-Apr;73A(2):173-189. doi: 10.6028/jres.073A.014.
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