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我们需要“离子吸附”氧物种吗?(或者,“基于可变表面氧空位浓度的金属氧化物气体敏感性的表面电导率模型”)。

Do We Need "Ionosorbed" Oxygen Species? (Or, "A Surface Conductivity Model of Gas Sensitivity in Metal Oxides Based on Variable Surface Oxygen Vacancy Concentration").

机构信息

Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, United Kingdom.

出版信息

ACS Sens. 2021 Oct 22;6(10):3509-3516. doi: 10.1021/acssensors.1c01727. Epub 2021 Sep 27.

DOI:10.1021/acssensors.1c01727
PMID:34570973
Abstract

The author provides an opinion on direct experimental evidence available to support the "ionosorption theory" often employed to interpret "electrophysical" measurements made during a gas sensing experiment. This article then aims to provide an alternative framework of a "surface conductivity" model based on recent advances in theoretical and experimental investigations in solid state physics, and to use this framework as a guide toward design rules for future improvement of gas sensor performance.

摘要

作者就支持“离子吸附理论”的直接实验证据提出了看法,该理论常用于解释气体传感实验中进行的“电动物理”测量。本文旨在提供一个基于固态物理学理论和实验研究最新进展的“表面导电性”模型的替代框架,并以此为指导,为未来提高气体传感器性能制定设计规则。

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