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以镁基复合材料为例的金属基复合材料中的组分界面类型

Types of Component Interfaces in Metal Matrix Composites on the Example of Magnesium Matrix Composites.

作者信息

Braszczyńska-Malik Katarzyna N

机构信息

Faculty of Production Engineering and Materials Technology, Institute of Materials Engineering, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa, Poland.

出版信息

Materials (Basel). 2021 Sep 9;14(18):5182. doi: 10.3390/ma14185182.

DOI:10.3390/ma14185182
PMID:34576403
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8471491/
Abstract

In this paper, a summary of investigations of the microstructure of cast magnesium matrix composites is presented. Analyses of the interfaces between the reinforcing particles and the magnesium alloy matrices were performed. Technically pure magnesium and four various alloys with aluminum and rare earth elements (RE) were chosen as the matrix. The composites were reinforced with SiC and Ti particles, as well as hollow aluminosilicate cenospheres. Microstructure analyses were carried out by light, scanning, and transmission electron microscopy. The composites with the matrix of magnesium and magnesium-aluminum alloys with SiC and Ti particles exhibited coherent interfaces between the components. In the composites based on ternary magnesium alloy with Al and RE with Ti particles, a high-melting AlRE phase nucleated on the titanium. Different types of interfaces between the components were observed in the composites based on the magnesium-rare earth elements alloy with SiC particles, in which a chemical reaction between the components caused formation of the ReSi phase. Intensive chemical reactions between the components were also observed in the composites with aluminosilicate cenospheres. Additionally, the influence of coatings created on the aluminosilicate cenospheres on the bond with the magnesium matrix was presented. A scheme of the types of interfaces between the components is proposed.

摘要

本文对铸造镁基复合材料的微观结构研究进行了总结。对增强颗粒与镁合金基体之间的界面进行了分析。选用工业纯镁以及四种含铝和稀土元素（RE）的不同合金作为基体。复合材料用碳化硅（SiC）颗粒、钛（Ti）颗粒以及空心硅铝酸盐微珠进行增强。通过光学显微镜、扫描电子显微镜和透射电子显微镜进行微观结构分析。以镁和含SiC与Ti颗粒的镁铝合金为基体的复合材料，其各组分之间呈现出连贯的界面。在以含铝和稀土元素的三元镁合金与Ti颗粒为基础的复合材料中，高熔点的AlRE相在钛上形核。在以含SiC颗粒的镁稀土元素合金为基础的复合材料中，观察到各组分之间存在不同类型的界面，其中各组分之间的化学反应导致形成了ReSi相。在含有硅铝酸盐微珠的复合材料中也观察到各组分之间发生了剧烈的化学反应。此外，还介绍了在硅铝酸盐微珠上形成的涂层对与镁基体结合的影响。提出了各组分之间界面类型的示意图。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/35e99c4553aa/materials-14-05182-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/9449a18ebb36/materials-14-05182-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/3b7771a4d077/materials-14-05182-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/2367df2a2704/materials-14-05182-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/585aa80f1444/materials-14-05182-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/dd69031640b6/materials-14-05182-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/a852af966105/materials-14-05182-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/0e2945064ac4/materials-14-05182-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/a5226ce35761/materials-14-05182-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/7d7879ec2ae6/materials-14-05182-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/35e99c4553aa/materials-14-05182-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/9449a18ebb36/materials-14-05182-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/3b7771a4d077/materials-14-05182-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/2367df2a2704/materials-14-05182-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/585aa80f1444/materials-14-05182-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/dd69031640b6/materials-14-05182-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/a852af966105/materials-14-05182-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/0e2945064ac4/materials-14-05182-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/a5226ce35761/materials-14-05182-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/7d7879ec2ae6/materials-14-05182-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7bac/8471491/35e99c4553aa/materials-14-05182-g010.jpg

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