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预制地聚合物浸水后的破坏机制

The Failure Mechanisms of Precast Geopolymer after Water Immersion.

作者信息

Wang Shunfeng, Yu Long, Xu Linglin, Wu Kai, Yang Zhenghong

机构信息

School of Materials Science and Engineering, Tongji University, 4800 Cao'an Road, Shanghai 201804, China.

Key Laboratory of Advanced Civil Engineering Materials, Tongji University, Ministry of Education, 4800 Cao'an Road, Shanghai 201804, China.

出版信息

Materials (Basel). 2021 Sep 14;14(18):5299. doi: 10.3390/ma14185299.

Abstract

Precast geopolymers with lower water/binder (0.14), which mainly consists of alkali solution, fly ash (FA) and steel slag (SS), were manufactured through molding pressing technology. The failure mechanisms of precast geopolymers after water immersion were studied by testing the loss of compressive strength, the pH of the leaching solution, the concentration of ions (Na, Ca, Si and Al), the evolution of phases, pore structure and morphology, and further discussion of the regulation evolution was performed. The results show that the harmful pores (>50 nm) of geopolymers progressively decrease from 70% to 50% after 28 days of water immersion when the content of steel slag increases from 0 to 80 wt.%. Compressive strength of geopolymers sharply reduces in the first 3 days and then increases during the water immersion process, but the phase composition varies slightly. Furthermore, increasing the content of steel slag could decrease the total porosity and further prevent the water resistance.

摘要

通过模压技术制备了水胶比(0.14)较低的预制地聚合物,其主要由碱溶液、粉煤灰(FA)和钢渣(SS)组成。通过测试抗压强度损失、浸出液的pH值、离子(Na、Ca、Si和Al)浓度、相演变、孔隙结构和形态,研究了预制地聚合物在水浸后的破坏机制,并对调控演变进行了进一步讨论。结果表明,当钢渣含量从0增加到80 wt.%时,水浸28天后地聚合物的有害孔隙(>50 nm)从70%逐渐减少到50%。地聚合物的抗压强度在水浸过程的前3天急剧降低,然后增加,但相组成变化不大。此外,增加钢渣含量可降低总孔隙率并进一步提高耐水性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1c08/8469394/3d0bd13af125/materials-14-05299-g001.jpg

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