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废玻璃粒径对基于粉煤灰的泡沫地质聚合物复合材料物理力学性能及孔隙率的影响

Influence of Waste Glass Particle Size on the Physico-Mechanical Properties and Porosity of Foamed Geopolymer Composites Based on Coal Fly Ash.

作者信息

Ziejewska Celina, Grela Agnieszka, Hebda Marek

机构信息

Faculty of Materials Engineering and Physics, Cracow University of Technology, Warszawska 24, 31-155 Cracow, Poland.

Faculty of Environmental and Power Engineering, Cracow University of Technology, Warszawska 24, 31-155 Cracow, Poland.

出版信息

Materials (Basel). 2023 Mar 1;16(5):2044. doi: 10.3390/ma16052044.

Abstract

In order to protect the environment and counteract climate change, it is necessary to take any actions that enable a reduction in CO emissions. One of the key areas is research focused on developing alternative sustainable materials for construction to reduce the global demand for cement. This work presents the properties of foamed geopolymers with the addition of waste glass as well as determined the optimal size and amount of waste glass for improving the mechanical and physical features of the produced composites. Several geopolymer mixtures were fabricated by replacing coal fly ash with 0%, 10%, 20%, and 30% of waste glass by weight. Moreover, the effect of using different particle size ranges of the addition (0.1-1200 µm; 200-1200 µm; 100-250 µm; 63-120 µm; 40-63 µm; 0.1-40 µm) in the geopolymer matrix was examined. Based on the results, it was found that the application of 20-30% of waste glass with a particle size range of 0.1-1200 µm and a mean diameter of 550 µm resulted in approximately 80% higher compressive strength in comparison to unmodified material. Moreover, the samples produced using the smallest fraction (0.1-40 µm) of waste glass in the amount of 30% reached the highest specific surface area (43.711 m/g), maximum porosity (69%), and density of 0.6 g/cm.

摘要

为了保护环境和应对气候变化,有必要采取任何能够减少一氧化碳排放的行动。关键领域之一是开展研究,重点是开发用于建筑的替代性可持续材料,以减少全球对水泥的需求。这项工作展示了添加废玻璃的泡沫地质聚合物的性能,并确定了废玻璃的最佳尺寸和用量,以改善所生产复合材料的机械和物理性能。通过用0%、10%、20%和30%(重量)的废玻璃替代粉煤灰,制备了几种地质聚合物混合物。此外,还研究了在地质聚合物基体中使用不同粒径范围(0.1 - 1200 µm;200 - 1200 µm;100 - 250 µm;63 - 120 µm;40 - 63 µm;0.1 - 40 µm)的添加剂的效果。基于这些结果,发现使用粒径范围为0.1 - 1200 µm、平均直径为550 µm的20% - 30%的废玻璃,与未改性材料相比,抗压强度提高了约80%。此外,使用30%的最小粒径级分(0.1 - 40 µm)的废玻璃制备的样品具有最高的比表面积(43.711 m/g)、最大孔隙率(69%)和0.6 g/cm的密度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6cc7/10004531/fbd346842b15/materials-16-02044-g001.jpg

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