High-Performance Hydrogel Adsorbent Based on Cellulose, Hemicellulose, and Lignin for Copper(II) Ion Removal.

Cellulose, hemicellulose, and lignin are three kinds of biopolymer in lignocellulosic biomass, and the utilization of the three biopolymers to synthesize hydrogel adsorbent could protect the environment and enhance the economic value of the biomass. A novel hydrogel adsorbent was prepared using cellulose, lignin, and hemicellulose of wheat straw by a one-pot method, and the adsorbent showed excellent adsorption performance for copper(II) ions. Scanning electron microscopy and Fourier transform infrared spectroscopy analysis showed that the prepared straw-biopolymer-based hydrogel had porous structure, and cellulose fibrils had crosslinked with lignin and hemicellulose by poly(acrylic acid) chains. The effects of contact time, initial concentration, and temperature on the copper(II) ion removal using the prepared hydrogels were investigated, and the obtained results indicated that the adsorption kinetics conformed to the pseudo-second-order and Elovich equation models and the adsorption isotherm was in accord with the Freundlich model. The adsorption thermodynamics study indicated that the adsorption process was spontaneous and accompanied by heat. X-ray photoelectron spectroscopy analysis revealed that the adsorption behavior resulted from ion exchange. The prepared hydrogel based on cellulose, hemicellulose, and lignin could be used for water treatment and soil remediation because of its high performances of excellent heavy metal ion removal and water retention.