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氧化石墨烯和SEBS-g-MAH增容剂对丙烯腈-丁二烯-苯乙烯/滑石粉复合材料力学性能和热性能的影响

The Effect of Graphene Oxide and SEBS-g-MAH Compatibilizer on Mechanical and Thermal Properties of Acrylonitrile-Butadiene-Styrene/Talc Composite.

作者信息

Joynal Abedin Fatin Najwa, Hamid Hamidah Abdul, Alkarkhi Abbas F M, Amr Salem S Abu, Khalil Nor Afifah, Ahmad Yahaya Ahmad Naim, Hossain Md Sohrab, Hassan Azman, Zulkifli Muzafar

机构信息

Green Chemistry and Sustainability Cluster, Branch Campus, Malaysian Institute of Chemical and Bioengineering, Technology University Kuala Lumpur, Taboh Naning, Alor Gajah, Melaka 78000, Malaysia.

Business School (UniKL BIS), University Kuala Lumpur, Kuala Lumpur 50250, Malaysia.

出版信息

Polymers (Basel). 2021 Sep 19;13(18):3180. doi: 10.3390/polym13183180.

Abstract

In this study, acrylonitrile butadiene styrene (ABS)/talc/graphene oxide/SEBS-g-MAH (ABS/Talc/GO/SEBS-g-MAH) and acrylonitrile butadiene styrene/graphene oxide/SEBS-g-MAH (ABS/GO/SEBS-g-MAH) composites were isolated with varying graphene oxide (0.5 to 2.0 phr) as a filler and SEBS-g-MAH as a compatibilizer (4 to 8 phr), with an ABS:talc ratio of 90:10 by percentage. The influences of graphene oxide and SEBS-g-MAH loading in ABS/talc composites were determined on the mechanical and thermal properties of the composites. It was found that the incorporation of talc reduces the stiffness of composites. The analyses of mechanical and thermal properties of composites revealed that the inclusion of graphene oxide as a filler and SEBS-g-MAH as a compatibilizer in the ABS polymer matrix significantly improved the mechanical and thermal properties. ABS/talc was prepared through melt mixing to study the fusion characteristic. The mechanical properties showed an increase of 30%, 15%, and 90% in tensile strength (TS), flexural strength (FS), and flexural modulus (FM), respectively. The impact strength (IS) resulted in comparable properties to ABS, and it was better than the ABS/talc composite due to the influence of talc in the composite that stiffens and reduces the extensibility of plastic. The incorporation of GO and SEBS-g-MA also shows a relatively higher thermal stability in both composites with and without talc. The finding of the present study reveals that the graphene oxide and SEBS-g-MAH could be utilized as a filler and a compatibilizer in ABS/talc composites to enhance the thermo-mechanical stability because of the superior interfacial adhesion between the matrix and filler.

摘要

在本研究中,以不同含量(0.5至2.0 phr)的氧化石墨烯作为填料、以SEBS-g-MAH作为增容剂(4至8 phr),制备了丙烯腈-丁二烯-苯乙烯共聚物(ABS)/滑石粉/氧化石墨烯/SEBS-g-MAH(ABS/Talc/GO/SEBS-g-MAH)和丙烯腈-丁二烯-苯乙烯共聚物/氧化石墨烯/SEBS-g-MAH(ABS/GO/SEBS-g-MAH)复合材料,其中ABS与滑石粉的比例为90:10(质量百分比)。研究了氧化石墨烯和SEBS-g-MAH的含量对ABS/滑石粉复合材料力学性能和热性能的影响。结果发现,滑石粉的加入降低了复合材料的刚度。复合材料力学性能和热性能分析表明,在ABS聚合物基体中加入氧化石墨烯作为填料和SEBS-g-MAH作为增容剂,显著改善了复合材料的力学性能和热性能。通过熔融共混制备了ABS/滑石粉复合材料以研究其熔融特性。力学性能方面,拉伸强度(TS)、弯曲强度(FS)和弯曲模量(FM)分别提高了30%、15%和90%。冲击强度(IS)与ABS相当,且由于复合材料中滑石粉的影响使塑料变硬并降低了延展性,其性能优于ABS/滑石粉复合材料。GO和SEBS-g-MA的加入在含滑石粉和不含滑石粉的两种复合材料中均表现出相对较高的热稳定性。本研究结果表明,由于基体与填料之间具有优异的界面粘附性,氧化石墨烯和SEBS-g-MAH可作为填料和增容剂用于ABS/滑石粉复合材料中,以提高其热机械稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e66/8472971/c2c62ca8157d/polymers-13-03180-g001.jpg

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