Department of Advanced Organic Materials Engineering, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon 305-764, South Korea.
Department of Advanced Organic Materials Engineering, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon 305-764, South Korea.
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Feb 5;266:120413. doi: 10.1016/j.saa.2021.120413. Epub 2021 Sep 25.
An easy to make xanthene based optical probe synthesized, precise recognition towards mercury ion been achieved by the probe RP and can detect Hg effectively in both for solid and liquid state with a vivid color change. The other tested ion showed no interference, visual and instrumental methods confirms the probe selectivity. Stoichiometry (1:1) confirmed by job's plot, plausible binding of Hg ion with the probe confirmed by mass and NMR studies. Test strip prepared for the prompt onsite detection in aqueous medium with outstanding color variation in daylight.
一种易于合成的香豆素基光学探针,通过探针 RP 对汞离子进行了精确识别,并能在固液两种状态下有效地检测 Hg,同时伴有明显的颜色变化。其他测试离子无干扰,通过目视和仪器方法证实了探针的选择性。通过 Job 作图法确定了化学计量比(1:1),通过质谱和 NMR 研究证实了 Hg 离子与探针的可能结合。制备了用于在水介质中即时现场检测的试纸条,在日光下具有出色的颜色变化。