Li Li, Huang Jin, Almutairi Adel W, Lan Xin, Zheng Linling, Lin Yuling, Chen Liudong, Fu Nanjie, Lin Zongren, Abomohra Abd El-Fatah
Department of Environmental Engineering, School of Architecture and Civil Engineering, Chengdu University, Chengdu, 610106 China.
Biological Sciences Department, Faculty of Science & Arts, King Abdulaziz University, Rabigh, Saudi Arabia.
Biomass Convers Biorefin. 2021 Sep 25:1-12. doi: 10.1007/s13399-021-01891-2.
Currently, the enormous generation of contaminated disposed face masks raises many environmental concerns. The present study provides a novel route for efficient crude bio-oil production from disposed masks through co-hydrothermal liquefaction (Co-HTL) with grown in wastewater. Ultimate and proximate analysis confirmed that contains relatively high nitrogen content (9.13%dw), which decreased by increasing the mask blend ratio. However, carbon and hydrogen contents were higher in masks (83.84 and 13.77%dw, respectively). In addition, masks showed 29.6% higher volatiles than , which resulted in 94.2% lower ash content. Thermal decomposition of masks started at a higher temperature (≈330 °C) comparing to (≈208 °C). The highest bio-oil yield was recorded by HTL of and Co-HTL with 25% () masks at 300 °C, which showed insignificant differences with each other. GC/MS analysis of the bio-oil produced from HTL of algal biomass showed a high proportion of nitrogen- and oxygen-containing compounds (3.6% and 11.9%, respectively), with relatively low hydrocarbons (17.4%). Mask blend ratio at 25% reduced the nitrogen-containing compounds by 55.6% and enhanced the hydrocarbons by 43.7%. Moreover, blending of masks with enhanced the compounds within the diesel range in favor of gasoline and heavy oil. Overall, the present study provides an innovative route for enhanced bio-oil production through mask recycling coupled with wastewater treatment.
The online version contains supplementary material available at 10.1007/s13399-021-01891-2.
目前,大量废弃口罩的产生引发了诸多环境问题。本研究提供了一种新途径,通过与生长在废水中的[具体物质未提及]进行共水热液化(Co-HTL),从废弃口罩中高效生产粗生物油。元素分析和工业分析证实,[具体物质未提及]含有相对较高的氮含量(9.13%干重),随着口罩混合比例的增加而降低。然而,口罩中的碳和氢含量较高(分别为83.84%和13.77%干重)。此外,口罩的挥发物含量比[具体物质未提及]高29.6%,灰分含量低94.2%。与[具体物质未提及](约208℃)相比,口罩的热分解起始温度更高(约330℃)。在300℃下,[具体物质未提及]的水热液化(HTL)以及与25%([具体物质未提及])口罩的共水热液化记录到最高生物油产率,二者之间无显著差异。对藻类生物质水热液化产生的生物油进行气相色谱/质谱(GC/MS)分析表明,含氮和含氧化合物比例较高(分别为3.6%和11.9%),碳氢化合物相对较低(17.4%)。25%的口罩混合比例使含氮化合物减少55.6%,碳氢化合物增加43.7%。此外,口罩与[具体物质未提及]混合有利于增加柴油范围内的化合物,生成汽油和重油。总体而言,本研究为通过口罩回收结合废水处理提高生物油产量提供了一条创新途径。
在线版本包含可在10.1007/s13399-021-01891-2获取的补充材料。