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非电力系统中废弃一次性口罩的热化学回收利用

Thermochemical recycling of waste disposable facemasks in a non-electrically powered system.

作者信息

Iwuozor Kingsley O, Emenike Ebuka Chizitere, Stephen Agbana Abiodun, Kevin Otoikhian Shegun, Adeleke Joy, Adeniyi Adewale George

机构信息

Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria.

Department of Chemical Engineering, University of Ilorin, P. M. B. 1515, Ilorin, Nigeria.

出版信息

Low Carbon Mater Green Constr. 2023;1(1):12. doi: 10.1007/s44242-023-00010-w. Epub 2023 Apr 4.

Abstract

The COVID-19 pandemic encouraged the use of plastic-based personal protective equipment (PPE), which aided greatly in its management. However, the increased production and usage of these PPEs put a strain on the environment, especially in developing and underdeveloped countries. This has led various researchers to study low-cost and effective technologies for the recycling of these materials. One such material is disposable facemasks. However, previous studies have only been able to engage electrically powered reactors for their thermochemical conversion, which is a challenge as these reactors cannot be used in regions with an insufficient supply of electricity. In this study, the authors utilized a biomass-powered reactor for the conversion of waste disposable facemasks and almond leaves into hybrid biochar. The reactor, which is relatively cheap, simple to use, environmentally friendly, and modified for biochar production, is biomass-powered. The co-carbonization process, which lasted 100 min, produced a 46% biochar yield, which is higher than previously obtained biochar yields by other researchers. The biochar thus obtained was characterized to determine its properties. FTIR analysis showed that the biochar contained functional groups such as alkenes, alkynes, hydroxyls, amines, and carbonyls. The EDX analysis revealed that the biochar was primarily made of carbon, tellurium, oxygen, and calcium in the ratios of 57%, 19%, 9%, and 7%, respectively. The inclusion of the facemask decreased the surface area and porosity of the biochar material, as evidenced by its surface area and pore characteristics.

摘要

新冠疫情促使人们使用塑料基个人防护装备(PPE),这对疫情防控起到了很大帮助。然而,这些个人防护装备产量和使用量的增加给环境带来了压力,尤其是在发展中国家和不发达国家。这促使众多研究人员探索低成本且有效的技术来回收这些材料。一次性口罩就是其中一种材料。然而,以往的研究仅能采用电动反应器对其进行热化学转化,而这存在一个难题,即这些反应器无法在电力供应不足的地区使用。在本研究中,作者利用生物质驱动的反应器将废弃一次性口罩和杏仁叶转化为混合生物炭。该反应器相对便宜、使用简便、环保且经过改造用于生物炭生产,是以生物质为动力的。持续100分钟的共碳化过程产生了46%的生物炭产率,这一产率高于其他研究人员之前获得的生物炭产率。对由此获得的生物炭进行了表征以确定其性质。傅里叶变换红外光谱(FTIR)分析表明,生物炭含有烯烃、炔烃、羟基、胺基和羰基等官能团。能量色散X射线光谱(EDX)分析显示,生物炭主要由碳、碲、氧和钙组成,其比例分别为57%、19%、9%和7%。如生物炭的表面积和孔隙特征所示,口罩的加入降低了生物炭材料的表面积和孔隙率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b418/10069943/7e335bcd3c88/44242_2023_10_Fig1_HTML.jpg

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