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基于软硬颗粒协同效应的超疏水涂层超低结冰附着力

Ultralow Icing Adhesion of a Superhydrophobic Coating Based on the Synergistic Effect of Soft and Stiff Particles.

作者信息

Cheng Houde, Yang Guiyan, Li Dan, Li Mengru, Cao Yang, Fu Qiang, Sun Youyi

机构信息

School of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China.

School of Civil and Environmental Engineering, University of Technology Sydney, Ultimo NSW 2007, Australia.

出版信息

Langmuir. 2021 Oct 19;37(41):12016-12026. doi: 10.1021/acs.langmuir.1c01626. Epub 2021 Oct 6.

Abstract

A novel superhydrophobic coating composed of soft polydimethylsiloxane microspheres and stiff SiO nanoparticles was developed and prepared. This superhydrophobic coating showed excellent superhydrophobicity with a large water contact angle of 171.3° and also exhibited good anti-icing performance and ultralow icing adhesion of 1.53 kPa. Furthermore, the superhydrophobic coating displayed good icing/deicing cycle stability, in which the icing adhesion was still less than 10.0 kPa after 25 cycles. This excellent comprehensive performance is attributed to stress-localization between ice and the surface, resulting from the synergistic effect of soft and stiff particles. This work thus opens a new avenue to simultaneously optimize the anti-icing and icephobic performance of a superhydrophobic surface for various applications.

摘要

开发并制备了一种由柔软的聚二甲基硅氧烷微球和坚硬的SiO纳米颗粒组成的新型超疏水涂层。这种超疏水涂层表现出优异的超疏水性,水接触角高达171.3°,还具有良好的防冰性能和1.53 kPa的超低结冰附着力。此外,该超疏水涂层具有良好的结冰/除冰循环稳定性,在25次循环后结冰附着力仍小于10.0 kPa。这种优异的综合性能归因于冰与表面之间的应力局部化,这是由软硬颗粒的协同作用产生的。因此,这项工作为同时优化超疏水表面在各种应用中的防冰和憎冰性能开辟了一条新途径。

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