Xuan Sensen, Yin Huan, Li Guoqiang, Zhang Zuxing, Jiao Yue, Liao Zhiwen, Li Jianhui, Liu Senyun, Wang Yuan, Tang Chengning, Wu Weiming, Li Guilin, Yin Kai
School of Manufacture Science and Engineering, School of Information Engineering, Key Laboratory of Testing Technology for Manufacturing Process, Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, People's Republic of China.
Key Laboratory of Icing and Anti/Deicing, China Aerodynamics Research and Development Center, Mianyang 621000, People's Republic of China.
ACS Nano. 2023 Nov 14;17(21):21749-21760. doi: 10.1021/acsnano.3c07385. Epub 2023 Oct 16.
Wind turbine blades are often covered with ice and snow, which inevitably reduces their power generation efficiency and lifetime. Recently, a superhydrophobic surface has attracted widespread attention due to its potential values in anti-icing/deicing. However, the superhydrophobic surface can easily transition from Cassie-Baxter to Wenzel at low temperature, limiting its wide applications. Herein, inspired by the excellent water resistance and cold tolerance of L. endowed by its micronano structure and low surface energy, a fresh structure was prepared by combining femtosecond laser processing technology and a boiling water treatment method. The prepared icephobic surface aluminum alloy (ISAl) mainly consists of a periodic microcrater array, nonuniform microclusters, and irregular nanosheets. This three-scale structure greatly promotes the stability of the Cassie-Baxter state. The critical Laplace pressure of ISAl is up to 1437 Pa, and the apparent water contact angle (CA) is higher than 150° at 0 °C. Those two factors contribute to its excellent anti-icing and deicing performances. The results show that the static icing delay time reaches 2577 s, and the ice adhesion strength is only 1.60 kPa. Furthermore, the anti-icing and deicing abilities of the proposed ISAl were examined under the environment of low temperature and high relative humidity to demonstrate its effectiveness. The dynamic anti-icing time of ISAl in extreme environments is up to 5 h, and ice can quickly fall with a speed of 34 r/min when it is in a horizontal rotational motion. Finally, ISAl has excellent reusability and mechanical durability, with the ice adhesion strength still being less than 6 kPa and the CA greater than 150° after 15 cycles of icing-deicing tests. The proposed structure would offer a promising strategy for the efficient anti-icing and deicing of wind turbine blades.
风力涡轮机叶片经常被冰雪覆盖,这不可避免地会降低其发电效率和使用寿命。近年来,超疏水表面因其在防冰/除冰方面的潜在价值而受到广泛关注。然而,超疏水表面在低温下很容易从卡西-巴克斯特状态转变为文泽尔状态,限制了其广泛应用。在此,受具有微米纳米结构和低表面能的荷叶优异的耐水性和耐寒性启发,通过飞秒激光加工技术和沸水处理方法相结合制备了一种新型结构。制备的憎冰表面铝合金(ISAl)主要由周期性微坑阵列、不均匀微簇和不规则纳米片组成。这种三尺度结构极大地促进了卡西-巴克斯特状态的稳定性。ISAl的临界拉普拉斯压力高达1437 Pa,在0°C时表观水接触角(CA)高于150°。这两个因素促成了其优异的防冰和除冰性能。结果表明,静态结冰延迟时间达到2577 s,冰附着力仅为1.60 kPa。此外,在低温高湿环境下对所提出的ISAl的防冰和除冰能力进行了测试,以证明其有效性。ISAl在极端环境下的动态防冰时间长达5 h,当处于水平旋转运动时,冰可以以34 r/min的速度迅速掉落。最后,ISAl具有优异的可重复使用性和机械耐久性,在15次结冰-除冰测试后,冰附着力仍小于6 kPa,CA大于150°。所提出的结构将为风力涡轮机叶片的高效防冰和除冰提供一种有前景的策略。