Starnovskaya Ekaterina S, Kopchuk Dmitry S, Shtaitz Yaroslav K, Savchuk Maria I, Nikonov Igor L, Egorov Ilya N, Zyryanov Grigory V, Rusinov Vladimir L, Chupakhin Oleg N
Ural Federal University, 620002, Yekaterinburg, Russian Federation.
I. Ya, Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620990, Yekaterinburg, Russian Federation.
J Fluoresc. 2022 Jan;32(1):125-133. doi: 10.1007/s10895-021-02759-4. Epub 2021 Oct 7.
A convenient synthetic approach to asymmetrically functionalized 1,3-di(2-pyridyl)benzenes starting from 3-(3-bromophenyl)-1,2,4-triazines using sequential aza-Diels-Alder reactions and Stille cross-coupling is reported. Photophysical properties of the obtained compounds are studied.
报道了一种从3-(3-溴苯基)-1,2,4-三嗪开始，利用连续的氮杂狄尔斯-阿尔德反应和施蒂勒交叉偶联反应，方便地合成不对称功能化的1,3-二(2-吡啶基)苯的方法。对所得化合物的光物理性质进行了研究。
