Faculty of Pharmacy, Department of Analytical Chemistry, Ankara University, Ankara, Turkey.
Crit Rev Anal Chem. 2023;53(4):798-824. doi: 10.1080/10408347.2021.1978055. Epub 2021 Oct 10.
Since the investigation of the properties of ionic liquids, there has been an increasing interest in these materials in the field of sensors area due to their unique properties. The electrochemical and radiolytic stability of ionic liquids are prerequisites for using ionic liquids. In addition, a large number of ionic liquids can be synthesized with the combination of different anions and cations. Therefore, they are preferred to fabricate the electrochemical, optical sensors, and biosensors or used in electrolyte solutions as they promise a facile and low-cost way to examine the analytes due to their properties such as increasing the conductivity, optical properties, and stability, lowering the detection limit, facilitating the electron transfer and increasing the effective surface area of the electrode and sensor platform. All of those properties are powered with the use of nanomaterials in the modification of the sensors. In this review, general information about the properties of ionic liquids were given. Moreover, the recent developments in electrochemical and optical sensor applications in the last five years were summarized. Finally, the utilization of ionic liquids and nanomaterials in the modification of the sensor platform and the advances of the proposed sensors for the analyses taking place in different molecules were discussed.
自从研究离子液体的性质以来,由于其独特的性质,这些材料在传感器领域越来越受到关注。离子液体的电化学和辐射稳定性是将其用于离子液体的先决条件。此外,通过不同的阴离子和阳离子的组合可以合成大量的离子液体。因此,它们被优先用于制备电化学、光学传感器和生物传感器,或者用作电解质溶液,因为它们具有增加电导率、光学性质和稳定性、降低检测限、促进电子转移以及增加电极和传感器平台的有效表面积等性质,从而为分析物的检测提供了一种简便且低成本的方法。所有这些性质都得益于纳米材料在传感器修饰中的应用。本文综述了离子液体的一般性质,并总结了过去五年电化学和光学传感器应用的最新进展。最后,讨论了离子液体和纳米材料在传感器平台修饰中的应用,以及用于分析不同分子的建议传感器的进展。