有机催化合成全氟苯硫醚——三甲基（全氟苯基）硅烷和硫代硫酸盐的硫醇化反应。
The organocatalytic synthesis of perfluorophenylsulfides the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates.
机构信息
Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur Autonomous Region, 832000, China.
Analysis and Testing Center of Shihezi University, Xinjiang Uygur Autonomous Region, 832000, China.
出版信息
Org Biomol Chem. 2021 Nov 3;19(42):9237-9241. doi: 10.1039/d1ob01350e.
The organic superbase -Bu-P-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% -Bu-P were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions.
有机超强碱 -Bu-P 催化的三甲基（全氟苯基）硅烷和硫代硫酸盐的直接硫代反应被开发出来。在 5mol% -Bu-P 的催化下，全氟苯硫醚的产率高达 97%。该方法在无金属的温和反应条件下，为构建全氟苯基-硫键提供了一种有效的方法。
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