Zhao Peng, Xia Jiahao, Liu Jianbing, Tan Yizheng, Ji Shaobo, Xu Huaping
Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China.
Innovative Centre for Flexible Devices (iFLEX), School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
ACS Appl Mater Interfaces. 2021 Oct 27;13(42):50422-50429. doi: 10.1021/acsami.1c15855. Epub 2021 Oct 15.
Remotely controlled on-demand functional healing is vital to components that are difficult to access and repair in distance such as satellites and unmanned cruising aircrafts. Compared with other stimuli, a blue laser is a better choice to input energy to the damaged area in distance because of its high energy density and low dissipation through the air. Herein, diselenide-containing polyurethane (PUSe) is first employed to fabricate visible light-responsive stretchable conductive composites with multiwalled carbon nanotubes (MWCNTs). Then, laser-induced remote healing was realized based on the characteristics of long-distance propagation of lasers and the dynamic properties of diselenide bonds. Moreover, the PUSe/MWCNT composite film can be used to transfer an electrical signal in the circuit containing a signal generator. This laser-induced remote healing of conductivity paves the way for developing healing conductors which are difficult to access and repair.
远程控制的按需功能修复对于诸如卫星和无人巡航飞机等难以接近和修复的部件至关重要。与其他刺激相比,蓝色激光因其高能量密度和在空气中的低耗散性,是向远处受损区域输入能量的更好选择。在此,首次采用含二硒化物的聚氨酯(PUSe)与多壁碳纳米管(MWCNT)制备可见光响应的可拉伸导电复合材料。然后,基于激光的长距离传播特性和二硒化物键的动态特性实现了激光诱导的远程修复。此外,PUSe/MWCNT复合膜可用于在包含信号发生器的电路中传输电信号。这种激光诱导的电导率远程修复为开发难以接近和修复的自愈导体铺平了道路。