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氧化锌作为光催化剂在去除水体系统中有机和无机污染物方面的制备、改性及工业应用的当前进展。

Current advancements on the fabrication, modification, and industrial application of zinc oxide as photocatalyst in the removal of organic and inorganic contaminants in aquatic systems.

作者信息

Abdullah F H, Bakar N H H Abu, Bakar M Abu

机构信息

Nanoscience Research Laboratory, School of Chemical Sciences, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

Nanoscience Research Laboratory, School of Chemical Sciences, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

出版信息

J Hazard Mater. 2022 Feb 15;424(Pt B):127416. doi: 10.1016/j.jhazmat.2021.127416. Epub 2021 Oct 6.

Abstract

Industrial wastewaters contain hazardous contaminants that pollute the environment and cause socioeconomic problems, thus demanding the employment of effective remediation procedures such as photocatalysis. Zinc oxide (ZnO) nanomaterials have emerged to be a promising photocatalyst for the removal of pollutants in wastewater owing to their excellent and attractive characteristics. The dynamic tunable features of ZnO allow a wide range of functionalization for enhanced photocatalytic efficiency. The current review summarizes the recent advances in the fabrication, modification, and industrial application of ZnO photocatalyst based on the analysis of the latest studies, including the following aspects: (1) overview on the properties, structures, and features of ZnO, (2) employment of dopants, heterojunction, and immobilization techniques for improved photodegradation performance, (3) applicability of suspended and immobilized photocatalytic systems, (4) application of ZnO hybrids for the removal of various types of hazardous pollutants from different wastewater sources in industries, and (5) potential of bio-inspired ZnO hybrid nanomaterials for photocatalytic applications using renewable and biodegradable resources for greener photocatalytic technologies. In addition, the knowledge gap in this field of work is also highlighted.

摘要

工业废水中含有有害污染物,这些污染物会污染环境并引发社会经济问题,因此需要采用光催化等有效的修复方法。氧化锌(ZnO)纳米材料因其优异且吸引人的特性,已成为去除废水中污染物的一种很有前景的光催化剂。ZnO的动态可调特性允许进行广泛的功能化以提高光催化效率。本综述基于对最新研究的分析,总结了ZnO光催化剂在制备、改性及工业应用方面的最新进展,包括以下几个方面:(1)ZnO的性质、结构和特性概述;(2)使用掺杂剂、异质结和固定化技术以提高光降解性能;(3)悬浮和固定光催化系统的适用性;(4)ZnO复合材料在去除工业中不同废水来源的各类有害污染物方面的应用;(5)受生物启发的ZnO复合纳米材料在光催化应用中使用可再生和可生物降解资源以实现更绿色光催化技术的潜力。此外,还强调了该工作领域的知识空白。

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