Ragunathan Thevaruban, Wood Colin D, Husin Hazlina
Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Seri Iskandar, Perak Darul Ridzuan Malaysia.
CSIRO Energy Business Unit, 26 Dick Perry Avenue, Kensington, WA 6102 Australia.
J Pet Explor Prod Technol. 2022;12(3):589-599. doi: 10.1007/s13202-021-01316-w. Epub 2021 Oct 12.
One of the major concerns during the production of crude oil especially in tropical waters is the deposition of wax on to the walls of the pipeline. This is due to the low seabed temperatures which can be below the wax appearance temperature (WAT) which leads to wax depositing out through molecular diffusion. Currently, there are many methods to prevent and remedy wax deposition but most of these solutions pose a serious environmental threat and are expensive to produce. Hence, this research investigated the use of an organic and cheaper alternative by utilizing synthetic fatty acid esters such as oleic acid which has shown promising results in reducing the pour point of waxy crude oils. The solution that was used was of palm oil origin, crude palm oil (CPO) and crude palm kernel oil (CPKO) and was subsequently compared with the pour point depressant and wax inhibition efficiency of the current industry used inhibitors utilizing the SETA Pour Point and Cloud Point as well as the cold finger apparatus. It was observed that the palm oil inhibitors were highly effective at 1 wt.% due to the high composition of oleic acid present portraying a similar result to Triethanolamine (TEA) while Ethylene Vinyl Acetate (EVA) performed best at low concentration of 0.1 wt.% but deteriorates significantly as the concentration increases due to the polar end agglomerating among itself.
在原油生产过程中,尤其是在热带水域,一个主要问题是蜡沉积在管道壁上。这是由于海底温度较低,可能低于蜡析出温度(WAT),导致蜡通过分子扩散析出。目前,有许多方法来防止和补救蜡沉积,但这些解决方案大多对环境构成严重威胁,且生产成本高昂。因此,本研究通过使用合成脂肪酸酯(如油酸)来研究一种有机且成本更低的替代方法,油酸在降低含蜡原油倾点方面已显示出有前景的结果。所使用的溶液源自棕榈油,即粗棕榈油(CPO)和粗棕榈仁油(CPKO),随后将其与当前行业使用的抑制剂的倾点降低和蜡抑制效率进行比较,采用SETA倾点和浊点以及冷指装置。观察到棕榈油抑制剂在1 wt.%时具有高效性,这是因为其中油酸含量高,呈现出与三乙醇胺(TEA)相似的结果,而乙烯醋酸乙烯酯(EVA)在0.1 wt.%的低浓度下表现最佳,但随着浓度增加,由于极性端自身聚集,性能显著恶化。