Li Hongfeng, Zhao Liwei, Qiao Yingjie, Bai Xuefeng, Wang Dezhi, Qu Chunyan, Liu Changwei, Wang Yongqiang
Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China.
College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China.
Polymers (Basel). 2021 Oct 11;13(20):3488. doi: 10.3390/polym13203488.
Surface treatment is typically required to improve the bonding performance of carbon-fiber-reinforced composites. Herein, a wet peel ply was prepared using bismaleimide (BMI) resins as a matrix resin. The temperature-heating rate extrapolation method and rheological method were employed to study the reaction characteristics and viscosity-temperature characteristics of the matrix in the BMI wet peel ply. The curing temperatures of the BMI wet peel ply and the BMI prepreg were the same (200 °C), making this wet peel ply suitable for co-curing with the BMI prepreg. After treatment with the wet peel ply, the bonding strength of the BMI composite joint showed a mean shear strength of 35.5 MPa, which was 1.72% higher than that of the sanded composite and 17.5% higher than that of the composite treated with the dry peel ply. In addition, the BMI composite treated with the BMI wet peel ply exhibited good bonding stability with a coefficient of variation of 3.9. After damp-heat aging for 1440 h, the retention rate of shear strength at room-temperature was 82.3%. The relatively loosely woven carrier in the BMI wet peel ply increased the surface roughness of the composite, thus improving the bonding strength.
通常需要进行表面处理以提高碳纤维增强复合材料的粘结性能。在此,使用双马来酰亚胺(BMI)树脂作为基体树脂制备了一种湿式脱模布。采用升温速率外推法和流变学法研究了BMI湿式脱模布中基体的反应特性和粘度-温度特性。BMI湿式脱模布和BMI预浸料的固化温度相同(200℃),这使得这种湿式脱模布适合与BMI预浸料共固化。用湿式脱模布处理后,BMI复合材料接头的粘结强度显示出平均剪切强度为35.5MPa,比打磨后的复合材料高1.72%,比用干式脱模布处理的复合材料高17.5%。此外,用BMI湿式脱模布处理的BMI复合材料表现出良好的粘结稳定性,变异系数为3.9。在湿热老化1440小时后,室温下剪切强度的保留率为82.3%。BMI湿式脱模布中相对疏松编织的载体增加了复合材料的表面粗糙度,从而提高了粘结强度。