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通过低压等离子体聚合工艺制备的用于鞋类的疏水皮革涂层

Hydrophobic Leather Coating for Footwear Applications by a Low-Pressure Plasma Polymerisation Process.

作者信息

Silvestre Carlos Ruzafa, Blasco María Pilar Carbonell, López Saray Ricote, Aguilar Henoc Pérez, Limiñana María Ángeles Pérez, Gil Elena Bañón, Calpena Elena Orgilés, Ais Francisca Arán

机构信息

Footwear Technology Centre, Campo Alto Campground, 03600 Alicante, Spain.

出版信息

Polymers (Basel). 2021 Oct 14;13(20):3549. doi: 10.3390/polym13203549.

DOI:10.3390/polym13203549
PMID:34685306
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8541137/
Abstract

The aim of this work is to develop hydrophobic coatings on leather materials by plasma polymerisation with a low-pressure plasma system using an organosilicon compound, such as hexamethyldisiloxane (HMDSO), as chemical precursor. The hydrophobic coatings obtained by this plasma process were evaluated with different experimental techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and standardised tests including colour measurements of the samples, surface coating thickness and water contact angle (WCA) measurements. The results obtained indicated that the monomer had polymerised correctly and completely on the leather surface creating an ultra-thin layer based on polysiloxane. The surface modification produced a water repellent effect on the leather that does not alter the visual appearance and haptic properties. Therefore, the application of the plasma deposition process showed promising results that makes it a more sustainable alternative to conventional functional coatings, thus helping to reduce the use of hazardous chemicals in the finishing process of footwear manufacturing.

摘要

这项工作的目的是通过使用有机硅化合物（如六甲基二硅氧烷（HMDSO））作为化学前驱体，利用低压等离子体系统在皮革材料上进行等离子体聚合，从而开发出疏水涂层。通过这种等离子体工艺获得的疏水涂层采用了不同的实验技术进行评估，如傅里叶变换红外光谱（FTIR）、X射线光电子能谱（XPS）、扫描电子显微镜（SEM）以及标准化测试，包括样品的颜色测量、表面涂层厚度和水接触角（WCA）测量。所获得的结果表明，单体已在皮革表面正确且完全地聚合，形成了基于聚硅氧烷的超薄层。这种表面改性对皮革产生了防水效果，且不会改变其视觉外观和触觉特性。因此，等离子体沉积工艺的应用显示出了有前景的结果，使其成为传统功能性涂层更具可持续性的替代方案，从而有助于减少鞋类制造整理过程中有害化学品的使用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/23423ccd9e8b/polymers-13-03549-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/cf758aa2f5f8/polymers-13-03549-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/3156800af4e3/polymers-13-03549-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/6049988bd019/polymers-13-03549-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/fef734ad5f1b/polymers-13-03549-g004a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/bb2d81990dc6/polymers-13-03549-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/04138bc60ca0/polymers-13-03549-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/685b5d97653b/polymers-13-03549-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/fbc7f33cc34e/polymers-13-03549-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/23423ccd9e8b/polymers-13-03549-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/cf758aa2f5f8/polymers-13-03549-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/3156800af4e3/polymers-13-03549-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/6049988bd019/polymers-13-03549-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/fef734ad5f1b/polymers-13-03549-g004a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/bb2d81990dc6/polymers-13-03549-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/04138bc60ca0/polymers-13-03549-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/685b5d97653b/polymers-13-03549-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/fbc7f33cc34e/polymers-13-03549-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ca/8541137/23423ccd9e8b/polymers-13-03549-g009.jpg

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