Gao Yu, Wang Guo-Lan, Jin Zi-Han, Zhang Jun, Geng Ya-Ni
Shaanxi Key Laboratory of Disaster Monitoring and Mechanism Simulation, Baoji University of Arts and Sciences, Baoji 721013, China.
Key Laboratory of Subsurface Hydrology and Ecological Effect in Arid Region of Ministry of Education, Chang'an University, Xi'an 710064, China.
Huan Jing Ke Xue. 2021 Nov 8;42(11):5333-5345. doi: 10.13227/j.hjkx.202102008.
The spatial distribution of heavy metals in rivers is affected by human activities and the natural environment, posing a risk to human health related to heavy metal pollution. In order to study the characteristics, health risk levels, and influencing factors of heavy metal distribution and pollution in the lower reaches of the Qianhe River, 19 surface sediments and 20 water samples were collected, and the contents of As, Cd, Cr, Cu, Mn, Ni, Pb, and Zn were measured by inductively coupled plasma mass spectrometry(ICP-MS). Using the DEM, air temperature, precipitation and other 11 factors as independent variables, the spatial differentiation of heavy metal pollution in sediments were explored based on geo-detector and geo-weighted regression model. The results showed that the eight heavy metal contents in the lower reaches of the Qianhe River did not exceed the "Surface Water Environmental Quality Standards" Ⅱ for water-like bodies, in which the variation coefficient of Pb element was 3.11, and the high content areas were mainly concentrated around Dongling Smelting Company and Fengxiang Railway Station. The average value of adult carcinogens in water bodies was 7.72 E-06, showing a low risk level, and the children's carcinogens average value was 1.17 E-04, showing a strong risk degree. The non-carcinogen risks for adults and children were both tolerable. The total high value for children was mainly concentrated around Fengxiang Railway Station, posing a high risk. Sedimentation of heavy metals, except As and Mn, exceeded the soil background value in Shaanxi Province. The average content of Cd element was 1.12 mg·kg, which was 12 times the soil background value in Shaanxi Province. The pollution of Cd, Zn, and Pb was high, and distributed mainly in Changqing Village, Nanwan Village and Niujiatan Village, Gaozhuang, and Dongling Smelting Company. PLI of heavy metals in the sediments in the study area was 1.71, which was light pollution. DEM, temperature and precipitation were the main natural factors influencing the spatial pattern of heavy metal pollution load index(PLI) in sediments, and their nonlinear interactions were enhanced, which may play a role in the spread of heavy metals in sediments. This research can provide a scientific basis for urban planning and human health risks prevention in the Qianhe River.
河流中重金属的空间分布受人类活动和自然环境影响,对与重金属污染相关的人类健康构成风险。为研究千河下游重金属分布与污染的特征、健康风险水平及影响因素,采集了19份表层沉积物和20份水样,采用电感耦合等离子体质谱法(ICP-MS)测定了砷、镉、铬、铜、锰、镍、铅和锌的含量。以数字高程模型(DEM)、气温、降水量等11个因素作为自变量,基于地理探测器和地理加权回归模型探讨了沉积物中重金属污染的空间分异。结果表明,千河下游8种重金属含量均未超过《地表水环境质量标准》Ⅱ类水质标准,其中铅元素变异系数为3.11,高含量区域主要集中在东岭冶炼公司和凤翔火车站附近。水体中成人致癌物平均值为7.72 E-06,风险水平较低,儿童致癌物平均值为1.17 E-04,风险程度较强。成人和儿童的非致癌物风险均可接受。儿童总高值主要集中在凤翔火车站附近,风险较高。除砷和锰外,其他重金属在沉积物中的含量均超过陕西省土壤背景值。镉元素平均含量为1.12 mg·kg,是陕西省土壤背景值的12倍。镉、锌、铅污染程度较高,主要分布在高庄的长青村、南湾村、牛家滩村以及东岭冶炼公司。研究区沉积物中重金属潜在生态风险指数(PLI)为1.71,属于轻度污染。DEM、温度和降水量是影响沉积物中重金属污染负荷指数(PLI)空间格局的主要自然因素,它们之间的非线性相互作用增强,可能对沉积物中重金属的扩散起作用。本研究可为千河流域城市规划和人类健康风险防控提供科学依据。