Zhang Xiu-Xiu, Lu Xiao-Li, Wei Yu-Chen, Zhu Chang-da, Pan Jian-Jun
College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095, China.
Huan Jing Ke Xue. 2021 Nov 8;42(11):5510-5518. doi: 10.13227/j.hjkx.202103161.
In order to assess the pollution of polycyclic aromatic hydrocarbons(PAHs) in a suburban farmland soil, 29 sampling sites were collected around Nanjing according to the grid method, and the contents of 15 different PAHs were determined. Acenaphthene(Ace) was not detected in any of the samples. The total content of PAHs in farmland soil ranged from 24.49 to 750.04 μg·kg, with an average of 226.64 μg·kg. The spatial distribution of high-ring PAHs, the main PAHs in the farmland soil, was similar to that of total PAHs. There was no significant correlation between PAHs and soil organic matter(SOM), pH, cation exchange capacity(CEC), and total nitrogen(TN), whereas bulk density and low ring PAHs were significantly correlated. The results of source apportionment show that the main source of PAHs in the farmland soil is a mixture of combustion and petroleum. The contamination severity index(CSI) index shows that the PAHs does not pose an ecological risk. The results of the health risk assessment show that there is no potential carcinogenic risk to children or adults, and the main sequence of exposure is skin contact>ingestion>inhalation.
为评估南京城郊农田土壤中多环芳烃(PAHs)的污染状况,采用网格法在南京周边采集了29个采样点,并测定了15种不同PAHs的含量。所有样品中均未检测到苊(Ace)。农田土壤中PAHs的总含量在24.49至750.04 μg·kg之间,平均为226.64 μg·kg。农田土壤中主要的PAHs——高环PAHs的空间分布与总PAHs相似。PAHs与土壤有机质(SOM)、pH、阳离子交换容量(CEC)和总氮(TN)之间无显著相关性,而容重与低环PAHs显著相关。源解析结果表明,农田土壤中PAHs的主要来源是燃烧源和石油源的混合。污染严重程度指数(CSI)表明PAHs未构成生态风险。健康风险评估结果表明,对儿童或成人不存在潜在致癌风险,主要暴露途径顺序为皮肤接触>摄入>吸入。