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中国吉林省主要水库周边农田土壤中的多环芳烃:分布、来源及潜在的人体健康风险

Polycyclic aromatic hydrocarbons in farmland soils around main reservoirs of Jilin Province, China: occurrence, sources and potential human health risk.

机构信息

Institute of Natural Disaster Research, School of Environment, Northeast Normal University, Changchun City, 130024, People's Republic of China.

出版信息

Environ Geochem Health. 2018 Apr;40(2):791-802. doi: 10.1007/s10653-017-0024-5. Epub 2017 Sep 30.

Abstract

Study on the occurrence, sources and potential human health risk of polycyclic aromatic hydrocarbons in farmland soils around reservoirs is of great significance for the people drinking water security. In the present study, representative farmland soil samples around main reservoirs of Jilin Province, China, were investigated for 16 PAHs. The total concentrations of 16 priority PAHs in 32 farmland soil samples ranged from 602.12 to 1271.87 ng/g, with an arithmetic average of 877.23 ng/g, and the sum of seven carcinogenic PAH concentrations ranged from 30.07 to 710.02 ng/g, with a mean value of 229.04 ng/g. The 3-ring and 4-ring PAHs were major exist and account for 45.78 and 32.03%, respectively. Non-cancer and cancer risk of pollutants were calculated, and the results indicate that the complex PAHs in farmland soils were not considered to pose significant health effects. The isomer ratios Fla/(Fla + Pyr) and BaA/(BaA + Chr) show that the PAHs in soils were generally derived from biomass and coal combustion.

摘要

研究水库周边农田土壤中多环芳烃的产生、来源及其对人体健康的潜在风险,对于保障人民饮水安全具有重要意义。本研究选取中国吉林省主要水库周边的代表性农田土壤样品,对 16 种多环芳烃进行了调查。32 个农田土壤样品中 16 种优先多环芳烃的总浓度范围为 602.12-1271.87ng/g,算术平均值为 877.23ng/g,7 种致癌多环芳烃浓度总和范围为 30.07-710.02ng/g,平均值为 229.04ng/g。3 环和 4 环多环芳烃是主要存在的,分别占 45.78%和 32.03%。计算了非致癌和致癌污染物的风险,结果表明,农田土壤中复杂的多环芳烃不太可能对健康产生显著影响。土壤中多环芳烃的异构体比值 Fla/(Fla + Pyr)和 BaA/(BaA + Chr)表明,土壤中的多环芳烃主要来源于生物质和煤燃烧。

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