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Ag/p-GaN欧姆接触退火条件的优化

Optimization of annealing conditions for Ag/p-GaN ohmic contacts.

作者信息

Pan Sai, Lu Youming, Liang Zhibin, Xu Chaojun, Pan Danfeng, Zhou Yugang, Zhang Rong, Zheng Youdou

机构信息

Jiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials and The School of Electronic Science and Engineering, Nanjing University, Nanjing, 210023 China.

Microfabrication and Integration Technology Center, Nanjing University, Nanjing, 210023 China.

出版信息

Appl Phys A Mater Sci Process. 2021;127(11):870. doi: 10.1007/s00339-021-05022-6. Epub 2021 Oct 25.

DOI:10.1007/s00339-021-05022-6
PMID:34720447
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8543412/
Abstract

The electrical and optical properties of Ag/p-GaN contacts have been investigated as a function of the annealing temperature, oxygen concentration, and annealing time. Specific contact resistance ( ) values as low as 1.2 × 10 Ω·cm were obtained from the Ag/p-GaN contact annealed at 400 °C for 60 s in ambient O/N (1:10). We found that the participation of oxygen improves the formation of ohmic contacts. Oxygen might remove the H in Mg-H complexes to activate the Mg acceptors and enhance Ga out-diffusion to form an Ag-Ga solid solution. We also found that the reflectivity of the Ag layer decreases with increasing annealing temperature in the O-containing ambient environment. Thus, an optimal annealing condition of Ag/p-GaN for blue and green LEDs is suggested based on these results. We also used the suggested annealing conditions to form ohmic contacts on DUV LEDs and achieved good electrical performance. The forward voltages of UVC LEDs fabricated with annealed Ag contacts were 6.60 V (7.66 V) at a 40 mA (100 mA) injection current.

摘要

研究了Ag/p-GaN接触的电学和光学性质与退火温度、氧浓度及退火时间的关系。在O/N(1:10)环境中于400℃退火60s的Ag/p-GaN接触获得了低至1.2×10Ω·cm的比接触电阻( )值。我们发现氧的参与改善了欧姆接触的形成。氧可能去除Mg-H络合物中的H以激活Mg受主并增强Ga的外扩散以形成Ag-Ga固溶体。我们还发现,在含O的环境中,Ag层的反射率随退火温度升高而降低。因此,基于这些结果提出了用于蓝色和绿色发光二极管的Ag/p-GaN的最佳退火条件。我们还使用所建议的退火条件在深紫外发光二极管上形成欧姆接触并获得了良好的电学性能。用退火Ag接触制备的深紫外发光二极管在40mA(100mA)注入电流下的正向电压为6.60V(7.66V)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/d69f991a1038/339_2021_5022_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/0f81bcacf875/339_2021_5022_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/f425309709c0/339_2021_5022_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/27618465ee5a/339_2021_5022_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/3ef3e668db7a/339_2021_5022_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/407371ab7738/339_2021_5022_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/3937689780e6/339_2021_5022_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/73aa304151d5/339_2021_5022_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/bbebdc15b0fd/339_2021_5022_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/d69f991a1038/339_2021_5022_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/0f81bcacf875/339_2021_5022_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/f425309709c0/339_2021_5022_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/27618465ee5a/339_2021_5022_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/3ef3e668db7a/339_2021_5022_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/407371ab7738/339_2021_5022_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/3937689780e6/339_2021_5022_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/73aa304151d5/339_2021_5022_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/bbebdc15b0fd/339_2021_5022_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/068b/8543412/d69f991a1038/339_2021_5022_Fig9_HTML.jpg

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本文引用的文献

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Integrating remote reflector and air cavity into inclined sidewalls to enhance the light extraction efficiency for AlGaN-based DUV LEDs.将远程反射器和空气腔集成到倾斜侧壁中以提高基于AlGaN的深紫外发光二极管的光提取效率。
Opt Express. 2020 May 25;28(11):17035-17046. doi: 10.1364/OE.393166.
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High Reliability of Ag Reflectors with AgCu Alloy for High Efficiency GaN-Based Light Emitting Diodes.
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