Zhu Jin, Yang Yiye, Yin Yanping, Yuan Huining
School of Electronic Information, Jiangsu University of Science and Technology, Zhengjiang, China.
School of Electronic Science and Technology, Xiamen University, Xiamen, China.
Front Chem. 2021 Oct 15;9:762638. doi: 10.3389/fchem.2021.762638. eCollection 2021.
This paper mainly studies the plasma optical properties of the silver nanorod and gold film system with gap structure. During the experiment, the finite element analysis method and COMSOL Multiphysics are used for modeling and simulation. The study changes the thickness of the PE spacer layer between the silver nanorod and the gold film, the conditions of the incident light and the surrounding environment medium. Due to the anisotropic characteristics of silver nanorod, the microcavity system is extremely sensitive to the changes of internal and external conditions, and the system exhibits strong performance along the long axis of the nanorod. By analyzing the extinction spectrum of the nanoparticle and the electric field section diagrams at resonance peak, it is found that the plasma optical properties of the system greatly depend on the gap distance, and the surrounding electric field of the silver nanorod is confined in the gap. Both ends of the nanorod and the gap are distributed with high concentrations of hot spots, which reflects the strong hybridization of multiple resonance modes. Under certain excitation conditions, the plasma hybridization behavior will produce a multi-pole mode, and the surface electric field distribution of the nanorod reflects the spatial directionality. In addition, the system is also highly sensitive to the environmental media, which will cause significant changes in its optical properties. The plasma microcavity system with silver nanorod and gold film studied in this paper can be used to develop high-sensitivity biosensors, which has great value in the field of biomedical detection.
本文主要研究具有间隙结构的银纳米棒与金膜系统的等离子体光学性质。实验过程中,采用有限元分析方法和COMSOL Multiphysics进行建模与仿真。研究改变了银纳米棒与金膜之间PE间隔层的厚度、入射光条件以及周围环境介质。由于银纳米棒的各向异性特征,该微腔系统对内部和外部条件的变化极为敏感,且系统沿纳米棒长轴表现出较强性能。通过分析纳米颗粒的消光光谱以及共振峰处的电场截面图,发现该系统的等离子体光学性质很大程度上取决于间隙距离,并且银纳米棒周围的电场被限制在间隙中。纳米棒两端以及间隙处均分布有高浓度热点,这反映了多种共振模式的强烈杂化。在一定激发条件下,等离子体杂化行为会产生多极模式,纳米棒的表面电场分布反映出空间方向性。此外,该系统对环境介质也高度敏感,这会导致其光学性质发生显著变化。本文所研究的具有银纳米棒与金膜的等离子体微腔系统可用于开发高灵敏度生物传感器,在生物医学检测领域具有重要价值。