一种挑战现有状况的新型铁氧物种。 - Suppr

A New Fe-oxo That Challenges the Status Quo.

作者信息

Hess Corinna R

机构信息

Department of Chemistry and Catalysis Research Center, Technical University of Munich, Lichtenbergstrasse 4, 85748, Garching, Germany.

出版信息

ACS Cent Sci. 2021 Oct 27;7(10):1608-1610. doi: 10.1021/acscentsci.1c01184. Epub 2021 Oct 12.

DOI:10.1021/acscentsci.1c01184

PMID:34729404

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8554780/

Abstract

摘要

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A New Fe-oxo That Challenges the Status Quo.一种挑战现有状况的新型铁氧物种。

ACS Cent Sci. 2021 Oct 27;7(10):1608-1610. doi: 10.1021/acscentsci.1c01184. Epub 2021 Oct 12.

Utilization of hydrogen bonds to stabilize M-O(H) units: synthesis and properties of monomeric iron and manganese complexes with terminal oxo and hydroxo ligands.利用氢键稳定M-O(H)单元：含端基氧代和羟基配体的单核铁和锰配合物的合成与性质

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Synthesis and characterization of anti-bisFe(III) porphyrins, syn-bisFe(III)-mu-oxo porphyrin, and syn-bisFe(III)-mu-oxo porphyrin cation radical.反双铁（III）卟啉、顺式双铁（III）-μ-氧代卟啉和顺式双铁（III）-μ-氧代卟啉阳离子自由基的合成与表征。

Inorg Chem. 2010 Apr 5;49(7):3449-60. doi: 10.1021/ic100002c.

Synthesis, Characterization, and Crystal Structure of a (&mgr;-Oxo)bis(&mgr;-acetato)diiron(III) Complex with a Dinucleating Hexapyridine Ligand, 1,2-Bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane. The First Example of a Discrete (&mgr;-Oxo)bis(&mgr;-acetato)diiron(III) Complex with a Dinucleating Ligand.

Inorg Chem. 1996 Aug 14;35(17):4967-4973. doi: 10.1021/ic9600994.

Trapping Iron(III)-Oxo Species at the Boundary of the "Oxo Wall": Insights into the Nature of the Fe(III)-O Bond.在“氧墙”边界捕获铁（III）-氧物种：对Fe（III）-O键本质的洞察

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Reaction of (mu-oxo)diiron(III) core with CO2 in N-methylimidazole: formation of mono(mu-carboxylato)(mu-oxo)diiron(III) complexes with N-methylimidazole as ligands.（μ-氧代）二铁（III）核心与N-甲基咪唑中二氧化碳的反应：形成以N-甲基咪唑为配体的单（μ-羧基）（μ-氧代）二铁（III）配合物。

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Use of Singlet Oxygen in the Generation of a Mononuclear Nonheme Iron(IV)-Oxo Complex.利用单线态氧生成单核非血红素铁（IV）-氧络合物。

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Lipoxygenase is irreversibly inactivated by the hydroperoxides formed from the enynoic analogues of linoleic acid.脂氧合酶会被由亚油酸的烯炔类似物形成的氢过氧化物不可逆地灭活。

Biochemistry. 1997 Apr 15;36(15):4480-8. doi: 10.1021/bi962956l.

Transmissible Burkholderia cepacia genomovar IIIa strains bind and convert monomeric iron(III) protoporphyrin IX into the mu-oxo oligomeric form.可传播的洋葱伯克霍尔德菌基因IIIa型菌株能结合单体铁（III）原卟啉IX并将其转化为μ-氧代寡聚体形式。

Microbiology (Reading). 2003 Apr;149(Pt 4):843-853. doi: 10.1099/mic.0.26160-0.

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Iron and manganese oxo complexes, oxo wall and beyond.铁和锰的含氧配合物、含氧壁及其他。

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Hydrocarbon Oxidation by an Exposed, Multiply Bonded Iron(III) Oxo Complex.通过暴露的、多重键合的铁（III）氧代配合物进行的烃类氧化反应。

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A Terminal Fe-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity.一个四核簇中的末端 Fe-Oxo：远端金属中心对结构和反应性的影响。

J Am Chem Soc. 2019 Jun 19;141(24):9479-9484. doi: 10.1021/jacs.9b03157. Epub 2019 Jun 10.

Trapping Iron(III)-Oxo Species at the Boundary of the "Oxo Wall": Insights into the Nature of the Fe(III)-O Bond.在“氧墙”边界捕获铁（III）-氧物种：对Fe（III）-O键本质的洞察

J Am Chem Soc. 2018 Oct 31;140(43):14391-14400. doi: 10.1021/jacs.8b08950. Epub 2018 Oct 18.

Facile nitrite reduction in a non-heme iron system: formation of an iron(III)-oxo.非血红素铁体系中易进行的亚硝酸盐还原：铁（III）-氧配合物的形成。

J Am Chem Soc. 2014 Dec 17;136(50):17398-401. doi: 10.1021/ja510615p. Epub 2014 Dec 3.

M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).强调三重对称性的铁和钴的M≡E及M=E配合物（E = O、N、NR）

Coord Chem Rev. 2011 Apr;255(7-8):920-937. doi: 10.1016/j.ccr.2011.01.009.

O2 activation by nonheme iron complexes: A monomeric Fe(III)-Oxo complex derived from O2.非血红素铁配合物对氧气的活化作用：一种由氧气衍生而来的单体Fe(III)-氧代配合物。

Science. 2000 Aug 11;289(5481):938-41. doi: 10.1126/science.289.5481.938.

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A New Fe-oxo That Challenges the Status Quo.

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