钌和铜催化的丙炔醇衍生物与腙的丙炔基取代反应。
Ruthenium- and Copper-Catalyzed Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Hydrazones.
机构信息
Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan.
Department of Applied Chemistry, School of Faculty of Pharmaceutical Sciences, Toho University, Miyama, Funabashi, Chiba, Japan.
出版信息
Chemistry. 2021 Nov 11;27(63):15562. doi: 10.1002/chem.202103784. Epub 2021 Nov 3.
Invited for the cover of this issue are Ken Sakata, Yoshiaki Nishibayashi, and co-workers at The University of Tokyo and Toho University. The image depicts the propargylic substitution reaction of a propargylic alcohol with an N-monosubstituted hydrazone, where the nucleophilicity of the hydrazone is controlled by the choice of catalytic system. Read the full text of the article at 10.1002/chem.202103287.
本期特邀封面人物是来自东京大学和东方大学的 Ken Sakata、Yoshiaki Nishibayashi 及其同事。该图片描绘了炔丙醇与 N-单取代腙的丙炔基取代反应，腙的亲核性由催化体系的选择来控制。阅读全文请点击 10.1002/chem.202103287。
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