Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Beijing, 100191, China.
School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.
Adv Mater. 2022 Jan;34(3):e2107243. doi: 10.1002/adma.202107243. Epub 2021 Nov 19.
Innovative multiplexing technologies based on nano-optics for anti-counterfeiting have been proposed as overt and covert technologies to secure products and make them difficult to counterfeit. However, most of these nano-optical anti-counterfeiting materials are metasurfaces and metamaterials with complex and expensive fabrication process, often resulting in materials that are not damage tolerant. Highly efficient anti-counterfeiting technologies with easy fabrication process are targeted for intuitive and effective authentication of banknotes, secure documents, and goods packing. Here, a simple strategy exploiting self-assembling and nanoimprinting technique to fabricate a composite lattice photonic crystal architecture featuring full spatial control of light, multiplexed full-pixel imaging, and multichannel cryptography combined with customized algorithms is reported. In particular, the real-time encryption/recognition of mobile quick response codes and anti-counterfeiting labels on a postage stamp, encoded by the proposed photonic architecture, are both demonstrated. The wave optics of scattering, diffraction, and polarization process involved are also described, validated with numerical simulations and experiments. By introducing a new degree of freedom in the 3D space, the multichannel image switching exhibits unprecedented variability of encryption, providing a promising roadmap to achieve larger information capacity, better security, and higher definition for the benefit of modern anti-counterfeiting security.
基于纳米光学的创新复用技术已被提出作为防伪的显形和隐形技术,以保护产品并使其难以伪造。然而,这些纳米光学防伪材料大多是具有复杂和昂贵制造工艺的超表面和超材料,通常导致材料不耐损坏。因此,目标是开发具有简单制造工艺的高效防伪技术,以直观有效地认证钞票、安全文件和商品包装。在这里,报告了一种利用自组装和纳米压印技术制造复合晶格光子晶体结构的简单策略,该结构具有完全空间控制的光、复用全像素成像以及多通道加密,结合了定制算法。特别地,展示了通过所提出的光子结构编码的移动快速响应码和邮票上的防伪标签的实时加密/识别。还描述了涉及的散射、衍射和偏振过程的波动光学,并通过数值模拟和实验进行了验证。通过在 3D 空间中引入新的自由度,多通道图像切换显示出前所未有的加密可变性,为实现更大的信息容量、更好的安全性和更高的清晰度提供了一条有前景的道路,从而有利于现代防伪安全。