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用于实现具有商业可行性的有机光伏的基于小分子的非富勒烯受体的设计与理解

Designs and understanding of small molecule-based non-fullerene acceptors for realizing commercially viable organic photovoltaics.

作者信息

Kim Minjun, Ryu Seung Un, Park Sang Ah, Pu Yong-Jin, Park Taiho

机构信息

RIKEN Center for Emergent Matter Science (CEMS) 2-1 Hirosawa, Wako Saitama 351-0198 Japan

Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH) 77 Cheongam-ro, Nam-gu Pohang Gyeongsangbuk-do 37673 Republic of Korea

出版信息

Chem Sci. 2021 Oct 12;12(42):14004-14023. doi: 10.1039/d1sc03908c. eCollection 2021 Nov 3.

DOI:10.1039/d1sc03908c
PMID:34760184
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8565376/
Abstract

Organic photovoltaics (OPVs) have emerged as a promising next-generation technology with great potential for portable, wearable, and transparent photovoltaic applications. Over the past few decades, remarkable advances have been made in non-fullerene acceptor (NFA)-based OPVs, with their power conversion efficiency exceeding 18%, which is close to the requirements for commercial realization. Novel molecular NFA designs have emerged and evolved in the progress of understanding the physical features of NFA-based OPVs in relation to their high performance, while there is room for further improvement. In this review, the molecular design of representative NFAs is described, and their blend characteristics are assessed statistical comparisons. Meanwhile, the current understanding of photocurrent generation is reviewed along with the significant physical features observed in high-performance NFA-based OPVs, while the challenging issues and the strategic perspectives for the commercialization of OPV technology are also discussed.

摘要

有机光伏（OPV）已成为一种有前途的下一代技术，在便携式、可穿戴和透明光伏应用方面具有巨大潜力。在过去几十年中，基于非富勒烯受体（NFA）的OPV取得了显著进展，其功率转换效率超过18%，接近商业实现的要求。在理解基于NFA的OPV的物理特性与其高性能之间的关系的过程中，新型分子NFA设计不断涌现和发展，不过仍有进一步改进的空间。在这篇综述中，描述了代表性NFA的分子设计，并通过统计比较评估了它们的共混特性。同时，回顾了目前对光电流产生的理解以及在高性能基于NFA的OPV中观察到的重要物理特性，还讨论了OPV技术商业化面临的挑战性问题和战略前景。

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