Zhao Gaoyuan, Li Juncheng, Wang Ting
Department of Chemistry, University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, USA.
Chem Commun (Camb). 2021 Nov 25;57(94):12659-12662. doi: 10.1039/d1cc04887b.
The development of visible-light-induced photoacid catalyzed glycosylation is reported. The eosin Y and PhSSPh catalyst system is applied to realize glycosylation with different glycosyl donors upon light irradiation. The reaction shows a broad substrate scope, including both glycosyl donors and acceptors, and highlights the mild nature of the reaction conditions.
报道了可见光诱导的光酸催化糖基化反应的进展。采用曙红Y和二苯基二硫醚催化剂体系，在光照下实现了与不同糖基供体的糖基化反应。该反应底物范围广泛，包括糖基供体和受体，并突出了反应条件温和的特点。
