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用于柔性电子应用的高功率紫外发光二极管模块光烧结银薄膜

Photo-Sintered Silver Thin Films by a High-Power UV-LED Module for Flexible Electronic Applications.

作者信息

Kim Minha, Jee Hongsub, Lee Jaehyeong

机构信息

Department of Electrical and Computer Engineering, Sungkyunkwan University, Suwon 16419, Korea.

出版信息

Nanomaterials (Basel). 2021 Oct 25;11(11):2840. doi: 10.3390/nano11112840.

Abstract

In recent printed electronics technology, a photo-sintering technique using intense pulsed light (IPL) source has attracted attention, instead of conventional a thermal sintering process with long time and high temperature. The key principle of the photo-sintering process is the selective heating of a thin film with large light absorption coefficients, while a transparent substrate does not heat by the IPL source. Most research on photo-sintering has used a xenon flash lamp as a light source. However, the xenon flash lamp requires instantaneous high power and is unsuitable for large area applications. In this work, we developed a new photo-sintering system using a high-power ultraviolet light emitting diode (UV-LED) module. A LED light source has many merits such as low power consumption and potential large-scale application. The silver nanoparticles ink was inkjet-printed on a polyethylene terephthalate (PET) and photo-sintered by the UV-LED module with the wavelength of 365 and 385 nm. The electrical resistivity as low as 5.44 × 10 Ω·cm (just about three times compared to value of bulk silver) was achieved at optimized photo-sintering conditions (wavelength of 365 nm and light intensity of 300 mW/cm).

摘要

在最近的印刷电子技术中,一种使用强脉冲光(IPL)源的光烧结技术引起了关注,它取代了传统的长时间高温热烧结工艺。光烧结过程的关键原理是选择性加热具有大光吸收系数的薄膜,而透明基板不会被IPL源加热。大多数关于光烧结的研究都使用氙闪光灯作为光源。然而,氙闪光灯需要瞬时高功率,不适合大面积应用。在这项工作中,我们开发了一种使用高功率紫外发光二极管(UV-LED)模块的新型光烧结系统。LED光源具有许多优点,如低功耗和潜在的大规模应用。将银纳米颗粒墨水喷墨打印在聚对苯二甲酸乙二酯(PET)上,并通过波长为365和385 nm的UV-LED模块进行光烧结。在优化的光烧结条件(波长365 nm,光强度300 mW/cm)下,实现了低至5.44×10Ω·cm的电阻率(仅约为块状银电阻率值的三倍)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a8a/8621171/8d67e26c326e/nanomaterials-11-02840-g001.jpg

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