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用于电磁干扰屏蔽材料的废木纤维素纤维/石墨烯纳米片碳纸的制备与表征

Fabrication and Characterization of Waste Wood Cellulose Fiber/Graphene Nanoplatelet Carbon Papers for Application as Electromagnetic Interference Shielding Materials.

作者信息

Park Jihyun, Kwac Lee Ku, Kim Hong Gun, Shin Hye Kyoung

机构信息

Institute of Carbon Technology, Jeonju University, 303 Cheonjam-ro, Wansan-gu, Jeonju-si 55069, Jeollabuk-do, Korea.

出版信息

Nanomaterials (Basel). 2021 Oct 28;11(11):2878. doi: 10.3390/nano11112878.

Abstract

Waste wood contains large amounts of cellulose fibers that have outstanding mechanical properties. These fibers can be recycled and converted into highly valuable materials of waste wood. In this study, waste wood cellulose fiber/graphene nanoplatelet (WWCF/GnP) papers were prepared according to the WWCF and GnP contents. Subsequently, the WWCF/GnP papers were varyingly carbonized for their application as electromagnetic interference (EMI) shielding materials such as state-of-the-art electronic equipment malfunction prevention, chip-level microsystem, and micro intersystem noise suppression/reduction. The increase in the GnP content and carbonization temperature enhanced electrical conductivity, thereby generating a greater EMI shielding effectiveness (EMI SE) in the high-frequency X-band. Additionally, the thickness of the WWCF/GnP carbon papers improved the electrical conductivity and EMI SE values. The electrical conductivity of the WWCF/GnP-15 carbon paper obtained at carbonization temperature of 1300 °C was approximately 5.86 S/m, leading to an EMI SE value of 43 decibels (dB) at 10.5 GHz for one sheet. Furthermore, overlapping of the three sheets increased the electrical conductivity to 7.02 S/m, leading to an EMI SE value of 72.5 dB at 10.5 GHz. Thus, we isolated WWCFs, without completely removing contaminants, for recycling and converting them into highly valuable EMI shielding materials.

摘要

废木材含有大量具有出色机械性能的纤维素纤维。这些纤维可以回收利用并转化为具有高价值的废木材材料。在本研究中,根据废木材纤维素纤维(WWCF)和石墨烯纳米片(GnP)的含量制备了废木材纤维素纤维/石墨烯纳米片(WWCF/GnP)纸。随后,对WWCF/GnP纸进行不同程度的碳化,以用作电磁干扰(EMI)屏蔽材料,如防止最先进的电子设备故障、芯片级微系统以及减少微系统间的噪声。GnP含量和碳化温度的增加提高了电导率,从而在高频X波段产生了更高的电磁干扰屏蔽效能(EMI SE)。此外,WWCF/GnP碳纸的厚度提高了电导率和EMI SE值。在1300℃碳化温度下获得的WWCF/GnP-15碳纸的电导率约为5.86 S/m,在10.5 GHz时一张纸的EMI SE值为43分贝(dB)。此外,三张纸重叠后电导率提高到7.02 S/m,在10.5 GHz时EMI SE值为72.5 dB。因此,我们在不完全去除污染物的情况下分离出WWCFs,以便回收利用并将其转化为具有高价值的EMI屏蔽材料。

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