Kang Hailan, Luo Sen, Du Hongyang, Han Lishuo, Li Donghan, Li Long, Fang Qinghong
College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China.
Key Laboratory for Rubber Elastomer of Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China.
Polymers (Basel). 2022 Feb 28;14(5):970. doi: 10.3390/polym14050970.
Herein, high-performance electromagnetic interference (EMI) shielding bio-based composites were prepared by using EUG ( gum) with a crystalline structure as the matrix and carbon nanotube (CNT)/graphene nanoplatelet (GNP) hybrids as the conductive fillers. The morphology of the CNT/GNP hybrids in the CNT/GNP/EUG composites showed the uniform distribution of CNTs and GNPs in EUG, forming a denser filler network, which afforded improved conductivity and EMI shielding effect compared with pure EUG. Accordingly, EMI shielding effectiveness values of the CNT/GNP/EUG composites reached 42 dB in the X-band frequency range, meeting the EMI shielding requirements for commercial products. Electromagnetic waves were mainly absorbed via conduction losses, multiple reflections from interfaces and interfacial dipole relaxation losses. Moreover, the CNT/GNP/EUG composites exhibited attractive mechanical properties and high thermal stability. The combination of excellent EMI shielding performance and attractive mechanical properties render the as-prepared CNT/GNP/EUG composites attractive candidates for various applications.
在此,通过使用具有晶体结构的EUG(树胶)作为基体,并以碳纳米管(CNT)/石墨烯纳米片(GNP)杂化物作为导电填料,制备了高性能电磁干扰(EMI)屏蔽生物基复合材料。CNT/GNP/EUG复合材料中CNT/GNP杂化物的形态表明,CNT和GNP在EUG中均匀分布,形成了更致密的填料网络,与纯EUG相比,这提高了导电性和EMI屏蔽效果。因此,CNT/GNP/EUG复合材料在X波段频率范围内的EMI屏蔽效能值达到42 dB,满足商业产品的EMI屏蔽要求。电磁波主要通过传导损耗、界面的多次反射和界面偶极弛豫损耗被吸收。此外,CNT/GNP/EUG复合材料表现出优异的机械性能和高热稳定性。优异的EMI屏蔽性能与吸引人的机械性能相结合,使得所制备的CNT/GNP/EUG复合材料成为各种应用的有吸引力的候选材料。