Surface Modified Activated Carbons: Sustainable Bio-Based Materials for Environmental Remediation.

Global warming and water/air contamination caused by human activities are major challenges in environmental pollution and climate change. The improper discharge of a large amount of agro-forest byproduct is accelerating these issues mainly in developing countries. The burning of agricultural byproducts causes global warming, whereas their improper waste management causes water/air pollution. The conversion of these waste materials into effective smart materials can be considered as a promising strategy in waste management and environmental remediation. Over the past decades, activated carbons (ACs) have been prepared from various agricultural wastes and extensively used as adsorbents. The adsorption capacity of ACs is linked to a well-developed porous structure, large specific surface area, and rich surface functional moieties. Activated carbon needs to increase their adsorption capacity, especially for specific adsorbates, making them suitable for specific applications, and this is possible by surface modifications of their surface chemistry. The modifications of surface chemistry involve the introduction of surface functional groups which can be carried out by various methods such as acid treatment, alkaline treatment, impregnation, ozone treatment, plasma treatment, and so on. Depending on the treatment methods, surface modification mainly affects surface chemistry. In this review, we summarized several modification methods for agricultural-waste-based ACs. In addition, the applications of AC for the adsorption of various pollutants are highlighted.