Li Hongjing, Xiong Yi, Wang Yumin, Ma Wenmei, Fang Jiapeng, Li Xu, Han Qing, Liu Yong, He Chunqing, Fang Pengfei
School of Physics and Technology, Key Laboratory of Nuclear Solid State Physics Hubei Province, Wuhan University, Wuhan 430072, China.
School of Physics and Technology, Key Laboratory of Nuclear Solid State Physics Hubei Province, Wuhan University, Wuhan 430072, China; Science and Technology Institute, Laboratory for Electron Microscopy, Wuhan Textile University, Wuhan 430073, China.
J Colloid Interface Sci. 2022 Mar;609:657-666. doi: 10.1016/j.jcis.2021.11.070. Epub 2021 Nov 17.
Piezocatalysis, driven by mechanical energy and piezoelectric effect, is of great potential in addressing the environmental issues. In this work, a piezoelectric catalyst was fabricated by growing few-layer MoS nanosheets onto CuS, for the piezocatalytic degradation of Rhodamine B (RhB), methylene blue (MB) and hexavalent chromium (Cr (VI)). The excellent removal efficiency of Cr (VI) and RhB can be reached 100% within 180 s, through the piezocatalysis of CuS/MoS-0.6 driven by mechanical stirring in the dark. Impressively, the piezoelectric current of CuS/MoS-0.6 is 48 and 35.7 times higher than that of pure CuS and MoS, respectively. The significantly enhanced piezocatalytic performance can be ascribed to the formation of CuS/MoS heterojunction and the piezoelectric field generated by MoS nanosheets, which promotes the efficient separation of electrons and holes. This study provides insights into strategies to improve catalytic performance through utilizing mechanical energy and opens a new horizon for environmental remediation.
由机械能和压电效应驱动的压电催化在解决环境问题方面具有巨大潜力。在这项工作中,通过在硫化铜上生长几层二硫化钼纳米片制备了一种压电催化剂,用于对罗丹明B(RhB)、亚甲基蓝(MB)和六价铬(Cr(VI))进行压电催化降解。在黑暗中通过机械搅拌驱动CuS/MoS-0.6的压电催化作用,Cr(VI)和RhB在180秒内的去除效率可达到100%。令人印象深刻的是,CuS/MoS-0.6的压电电流分别比纯硫化铜和二硫化钼高48倍和35.7倍。显著增强的压电催化性能可归因于CuS/MoS异质结的形成以及二硫化钼纳米片产生的压电场,这促进了电子和空穴的有效分离。本研究为通过利用机械能提高催化性能的策略提供了见解,并为环境修复开辟了新的前景。