School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai, PR China.
J Sci Food Agric. 2022 Jul;102(9):3572-3580. doi: 10.1002/jsfa.11703. Epub 2021 Dec 16.
This study reports the formation of sacha inchi oil (SIO) microemulsions for food and cosmetic applications. Effects of non-ionic surfactants, short-chain alcohols, essential oil and straight-chain esters on the phase behavior and formulation of U-type microemulsion were investigated. Pseudo ternary phase diagrams were constructed to assess the influence of these factors using water titration method. Structural transitions were measured along several water dilution lines using conductivity and viscosity tools.
Among four different surfactants, Tween 80 solubilized the maximum oil and induced the formation of a U-type microemulsion system. Oil solubilization was decreased in the presence of short-chain alcohols. In addition, the system containing straight-chain esters as the cosolvent showed a higher expansion effect in the U-type areas than that containing essential oils. Finally, upon water dilution of three systems with SIO/ethyl acetate of 1:1, 1:2 and 1:3, microstructural transition from W/O to bicontinuous occurred at 200 g kg (w/w) water content, and then to O/W structure at 650 g kg (w/w) water content.
Straight-chain esters as cosolvent is a potential strategy to extend the dilutability of SIO microemulsions. © 2021 Society of Chemical Industry.
本研究报告了沙棘油(SIO)微乳液的形成,可应用于食品和化妆品。考察了非离子表面活性剂、短链醇、精油和直链酯对 U 型微乳液相行为和配方的影响。使用水滴定法通过伪三元相图构建来评估这些因素的影响。使用电导率和粘度仪沿几条水稀释线测量结构转变。
在四种不同的表面活性剂中,吐温 80 增溶了最大量的油,并诱导形成 U 型微乳液体系。短链醇的存在降低了油的增溶。此外,含有直链酯作为共溶剂的体系在 U 型区域中的扩展效果高于含有精油的体系。最后,在将含有 SIO/乙酸乙酯为 1:1、1:2 和 1:3 的三个体系用水稀释时,在 200 g kg(w/w)水含量时从 W/O 到双连续微结构发生转变,然后在 650 g kg(w/w)水含量时转变为 O/W 结构。
直链酯作为共溶剂是扩展 SIO 微乳液稀释性的一种有潜力的策略。 © 2021 英国化学学会。