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利用超细气泡研究稀释盐溶液的琼斯 - 雷效应。

Utilization of Ultrafine Gas Bubbles to Investigate the Jones-Ray Effect of Diluted Salt Solutions.

作者信息

Phan Thy D U, Phan An H T, Le Khoa C M, Le Thi H, Nguyen Khoi T

机构信息

School of Biotechnology, International University, Vietnam National University of Ho Chi Minh City, Ho Chi Minh City 700000, Vietnam.

School of Chemical Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.

出版信息

Langmuir. 2021 Dec 14;37(49):14237-14242. doi: 10.1021/acs.langmuir.1c01515. Epub 2021 Dec 4.

Abstract

The cause of the Jones-Ray effect has been controversially debated for years. Ultrafine gas bubbles were employed to lessen the surface excess of the surface-active impurities adsorbing to the air/water interface of the salt solutions, which would lead to a direct shift in surface tension observable by the Wilhelmy plate method. It was concluded in this study that once the surface excess of the inevitable impurities in the salts is lessened by the introduction of ultrafine gas bubbles, which possess great air/water interfacial area, the Jones-Ray effect becomes nonobservable. Therefore, our finding hypothesized that the Jones-Ray effect might not originate from salts.

摘要

琼斯 - 雷效应的成因多年来一直存在争议。人们使用超细气泡来减少吸附在盐溶液空气/水界面的表面活性杂质的表面过剩量,这会导致通过威尔海姆板法可观察到表面张力的直接变化。本研究得出的结论是,一旦通过引入具有很大空气/水界面面积的超细气泡来减少盐中不可避免的杂质的表面过剩量,琼斯 - 雷效应就变得不可观察到。因此,我们的发现假设琼斯 - 雷效应可能并非源于盐。

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