Kansiz Sevgi, Gul Adem, Dege Necmi, Agar Erbil, Saif Eiad
Samsun University, Faculty of Engineering, Department of Fundamental Sciences, 55420, Samsun, Turkey.
Akay Pharma Medicine and Health Products Industries & Trade, 34000, Istanbul, Turkey.
Acta Crystallogr E Crystallogr Commun. 2021 Oct 13;77(Pt 11):1087-1090. doi: 10.1107/S2056989021010215. eCollection 2021 Nov 1.
The title compound, CHNO, is a Schiff base that exists in the enol-imine tautomeric form and adopts a configuration. The mol-ecule is non-planar, with the twisted rings making a dihedral angle of 39.92 (4)°. The intra-molecular O-H⋯N hydrogen bond forms an (6) ring motif. In the crystal, mol-ecules are linked by C-H⋯π inter-actions and very weak π-π stacking inter-actions also help to consolidate the crystal packing. A Hirshfeld surface analysis was performed to investigate the contributions of different inter-molecular contacts within the supra-molecular structure. The major contributions are from H⋯H (65%), C⋯H (19.2%) and O⋯H (6.6%) inter-actions.
标题化合物CHNO是一种席夫碱,以烯醇-亚胺互变异构形式存在并采用一种构型。分子是非平面的,扭曲的环形成39.92 (4)°的二面角。分子内的O-H⋯N氢键形成一个(6)环基序。在晶体中,分子通过C-H⋯π相互作用相连,非常弱的π-π堆积相互作用也有助于巩固晶体堆积。进行了 Hirshfeld 表面分析以研究超分子结构内不同分子间接触的贡献。主要贡献来自H⋯H(65%)、C⋯H(19.2%)和O⋯H(6.6%)相互作用。