Light-enabled alkenylation of iodocarboranes with unactivated alkenes.
作者信息
Ni Hangcheng, Lu Zhenpin, Xie Zuowei
机构信息
Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin N. T., Hong Kong, China.
出版信息
Dalton Trans. 2021 Dec 20;51(1):104-110. doi: 10.1039/d1dt03726a.
PMID:34870668
Abstract
The synthesis of alkenylated--carboranes photoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate scope and good functional group tolerance. Control experiments suggest that the reaction may involve the cage C-centered radical species.
摘要
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