[1,1'-双（-碳硼烷）]双（膦）钌配合物中的'-Ru到'-Ru异构化
,'-Ru to ,'-Ru isomerisation in bis(phosphine)Ru complexes of [1,1'-bis(-carborane)].
作者信息
Jeans Rebekah J, Rosair Georgina M, Welch Alan J
机构信息
Institute of Chemical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, UK.
出版信息
Chem Commun (Camb). 2021 Dec 21;58(1):64-67. doi: 10.1039/d1cc06119d.
PMID:34873603
Abstract
We report herein the first example of the controlled isomerisation of a ,'-bound (to metal) bis(-carborane) ligand to ,'-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned.
摘要
我们在此报告首例（与金属）以α，α'-键合的双（碳硼烷）配体可控异构化为以α，β'-键合且分子中无其他变化的情况。由于碳硼烷的碳和硼顶点具有不同的给电子性质，这种转变能够对金属中心的反应活性进行微调。
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