Faculty of Life and Environmental Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8572, Ibaraki, Japan.
Research Center for Chemistry, National Research and Innovation Agency Republic of Indonesia, Puspiptek Area, Serpong 15314, Indonesia.
Molecules. 2021 Nov 26;26(23):7171. doi: 10.3390/molecules26237171.
Considering the toxicity of the impurities of synthesized anthraquinone, this study clarified new catalytic compounds for kraft cooking with improved carbohydrate yield and delignification and less mutagenicity, which are important for ensuring the safety of paper products in contact with food. The 2-methylanthraquinone contents of teak () woods were 0.18-0.21%. Acetone extracts containing 2-methylanthraquinone from Myanmar and Indonesia teak woods as additives improved lignin removal during kraft cooking of eucalyptus wood, which resulted in kappa numbers that were 2.2-6.0 points lower than the absence of additive. Myanmar extracts and 2-methylanthraquinone improved carbohydrate yield in pulps with 1.7-2.2% yield gains. Indonesia extracts contained more deoxylapachol and its isomer than 2-methylanthraquinone. The residual content of 2-methylanthraquinone in the kraft pulp was trace. Although Ames tests showed that the Indonesia and Myanmar extracts were mutagenic to , 2-methylanthraquinone was not. The kraft pulp obtained with the additives should be safe for food-packaging applications, and the addition of 0.03% 2-methylanthraquinone to kraft cooking saves forest resources and fossil energy in industries requiring increased pulp yield.
考虑到合成蒽醌杂质的毒性,本研究阐明了新的 kraft 蒸煮催化化合物,可提高碳水化合物得率和脱木质素率,降低致突变性,这对于确保接触食品的纸制品的安全性非常重要。柚木( )木材中的 2-甲基蒽醌含量为 0.18-0.21%。作为添加剂,来自缅甸和印度尼西亚柚木的含 2-甲基蒽醌的丙酮提取物可改善桉木 kraft 蒸煮过程中的木质素去除,从而使卡伯值比无添加剂时低 2.2-6.0 点。缅甸提取物和 2-甲基蒽醌可提高纸浆的碳水化合物得率,使产率提高 1.7-2.2%。印度尼西亚提取物比 2-甲基蒽醌含有更多的去氧拉帕醇及其异构体。废 kappa 浆中 2-甲基蒽醌的残留量很少。虽然 Ames 试验表明印度尼西亚和缅甸提取物对 有致突变性,但 2-甲基蒽醌没有。用添加剂获得的 kraft 浆对于食品包装应用是安全的,并且在 kraft 蒸煮中添加 0.03%的 2-甲基蒽醌可节省需要提高纸浆产量的行业中的森林资源和化石能源。